89th Canadian Chemistry Conference Abstracts


Organic Chemistry Division

Sunday AM

OR8CC-Mariner 4

Organic Reaction Mechanisms

Organizer(s) - James Pincock and Frances Cozens
Chair(s) - James Pincock

08:20 00097 Aromatic versus Acyclic Dienyl Propargyldicobalt Cations. Preparation and Comparative Reactivity Amiralaei S., Green J.R.
08:40 00098 A Tale of Two Silenes: A Comparison of the Reactivity of Brook- and Wiberg-Type Silenes Baines‡ K.M., Milnes K.K., Gottschling S.E.
09:20 00099 The Reactions of Transient Germylenes with Alcohols and Ethers Lollmahomed F.B., Harrington C.R., McDonald J., Leigh W.J.
09:40 Coffee Break
10:00 00100 Formation of Metallaoxetanes: C-O Bond Activation of 1,2-Epoxybutane by Ground-State Ga Atoms Joly H.A., Beaudet L.
10:20 00101 A New Approach to Mechanistic Analysis. Estimation of Hammett q or Taft q* Values by a Simple Procedure Guthrie J.P.
10:40 00102 Dynamics of Ion-Pair Intermediates of Solvolysis in Water Richard‡ J.P., Amyes T.L., Toteva M.M., Tsuji Y.
11:20 End of Session


REMINDER
11:25 Montreal Medal Lecture presented by Richard Puddephatt in CC-Port Royal C1

OR9CC-Mariner 5

Peptide Science (Joint with BM) (joint with BM9)

Organizer(s) - William Lubell
Chair(s) - Robert Ben

09:00 Joint with Biological and Medicinal Chemistry Division - See BM9

11:20 End of Session


REMINDER
11:25 Montreal Medal Lecture presented by Richard Puddephatt in CC-Port Royal C1

OR10CC-Port Royal C1

Recent Advances in Organic Synthesis

Organizer(s) - Jean Burnell and Ian Pottie
Chair(s) - Jean Burnell

08:20 00103 Total Syntheses of the Xyloketal Natural Products Wilson‡ P.D.
09:00 00104 Adventures in Synthetic Methods Using Strained Intermediates Yudin‡ A.K.
09:40 Coffee Break
10:00 00105 New Annulation and Cycloaddition Strategies for the Synthesis of Heterocyclic Compounds Danheiser‡ R.L.
10:40 00106 An Enantioselective Synthesis of the Carbon Skeleton of Penostatin F Ang P.J.A., Barriault L.
11:00 00107 A New Acyclic Strategy for the Synthesis of Nucleoside Analogs Prevost M., Chapdelaine D., Waltz M.-E., Guindon Y.
11:20 End of Session


REMINDER
11:25 Montreal Medal Lecture presented by Richard Puddephatt in CC-Port Royal C1


Sunday PM

OR2CC-Mariner 5

Heterocycles and Heteroatom-Containing Rings

Organizer(s) - Alison Thompson
Chair(s) - Alison Thompson

13:40 00332 Design Synthesis and Evaluation of Heterocyclic Ligands and Catalysts for Asymmetric Reactions Wilson P.D.
14:00 00333 Efficient 3-Component Synthesis of Pyrroles: The Development of a new Class of 1,3-Dipolar Heterocycles St.Cyr D.J., Dhawan R., Arndtsen B.A.
14:20 00334 Münchnones and Azomethine Ylids in New Cascades of Intramolecular Reactions Leading to Bi- and Tricyclic Adducts Belanger G., April M., Dauphin E., Lévesque F., Roy S.
14:40 00335 A Tandem Cyclopropanation/Cyclopropane Rearrangement/1,3-Dipolar Cycloaddition in the Synthesis of Functionalized c-Lactams Kendall C., Wurz R.P., Charette A.B.
15:00 Coffee Break
15:20 00336 An Efficient Regiospecific Synthesis of Pyrroles and Related Heterocycles by the Annulation of Nitriles with Donor-Acceptor Cyclopropanes Pagenkopf‡ B.L.
16:00 00337 Indole N-CONEt2 DreM Migration. Toward a Total Synthesis of Furostifoline Zhao Z.D., Snieckus V.
16:20 End of Session


REMINDER
16:20 R.U. Lemieux Award Lecture presented by André Charette in CC-Port Royal C1

OR3CC-Mariner 4

Innovative Chemistry in Novel Media

Organizer(s) - Robert Singer
Chair(s) - Robert Singer

13:40 00338 Approaches to Crystallization from Ionic Liquids: Complex Solvents-Complex Results or A Strategy for Controlled Formation of New Supramolecular Architectures Rogers‡ R.D., Reichert W.M.
14:20 00339 Electron Rich Ionic Liquids: New Chemistry and Applications Clyburne‡ J.A.C.
15:00 Coffee Break
15:20 00340 The Role of Co-Crystals in Pharmaceutical Science and Solid-State Synthesis Zaworotko‡ M.J., Cheney M., Gherco O., Peddy V.
16:00 00341 Functionalization of Imidazolium Salts with Amino Diacetic Acid Groups Harjani J., Singer R.
16:20 End of Session


REMINDER
16:20 R.U. Lemieux Award Lecture presented by André Charette in CC-Port Royal C1

OR9CC-Highland 10

Peptide Science (Joint with BM) (joint with BM9)

Organizer(s) - William Lubell
Chair(s) - David Perrin

13:40 Joint with Biological and Medicinal Chemistry Division - See BM9

16:20 End of Session


REMINDER
16:20 R.U. Lemieux Award Lecture presented by André Charette in CC-Port Royal C1

OR10CC-Port Royal C1

Recent Advances in Organic Synthesis

Organizer(s) - Jean Burnell and Ian Pottie
Chair(s) - Mike Chong

13:40 00342 Rhodium-Catalyzed C-H Insertion of Nitrene Intermediates Huard K., Lebel H.
14:00 00343 Synthetic Approaches to (+)-Halenaquinone and (+)-Virdin Gorobets E., Hopkins J.M., Lucciola D., Wheatley B.M.M., Keay‡ B.A.
14:40 00344 Enantioselective Synthesis of Functionalized Cyclohexanes and Medium-Sized Oxacycles and Carbocycles Pansare S.V., Adsool V.A.
15:00 Coffee Break
15:20 00345 An Unprecedented Regioselective Intermolecular Pd-Catalyzed Cross-Coupling Reaction Employing Heterocyclic Carboxylic Acids with Aryl Halides Bilodeau F., Brochu M.-C., St-Onge M., Forgione P.
15:40 00346 Towards the Total Synthesis of Cervinomycin and its Derivatives Anctil E.J.-G., Nolte B., Hartung C.G., Igancio Diez R., Snieckus V.
16:00 00347 A Stereodivergent Synthesis of Virantmycin Wulff J.E., Back T.G.
R.U. Lemieux Award Lecture presented by André Charette

Introduction of André Charette by Hélène Lebel

16:20 00348 New Methods for the Stereoselective Synthesis of Organic Compounds Charette‡ A.B.
17:00 End of Session

ORPCC-Port Royal D,E

Posters

Organizer(s) - Bruce Grindley
Chair(s) - Bruce Grindley

From 17:00 until 19:00

17:00 00349 Phase Switch Chemistry with N,N-Diethanolaminomethyl Polystyerene Resin and Boronic Acids as Convertible Tags Mothana S., Chahal N., Vanneste S., Hall* D.G.
17:00 00350 Regioselective Preparation of 3-Substituted b-Naphthols, 1,3 and 3,4-Disubstituted b-Naphthols via Directed ortho Metalation (DoM) Morin J.A., Snieckus V.
17:00 00351 New Aromatic Anionic Synthetic Methods: Towards the Total Synthesis of Schumanniophytine Macklin T., Snieckus V.
17:00 00352 Synthetic Approaches Towards (+)-Halenaquinone Lucciola D., Keay B.A.
17:00 00353 Synthetic Uses of Novel P-Chiral Spiro Oxazaphosphinanes Lines W.L., Keay B.A.
17:00 00354 A Simple and Expeditious Synthesis of No-Carrier Added 11C-Methylamine for Application in Positron Emission Tomography (PET) Radiotracer Synthesis Lakhrissi Y., Mzengeza S., Soucy J.-P., Jean-Claude B.
17:00 00355 Synthesis of 2-Hydroxy-1-(1-phenyltetralyl)piperidine and Some of its Intermediates as the Derivatives of Phencyclidine Kassiri M., Ahmadi A., Fathollahi Y.
17:00 00356 Geminal Acylation with a Facially Biased Acyloin Hughes J.A., Burnell D.J.
17:00 00357 Copper Catalyzed Formation of Enol Ester from Potassium Trifluoroborate and Carboxylate Salts or Carboxylic Acids Huang F., Quach T.D., Batey R.A.
17:00 00358 Kinetics, Mechanism and Regioselectivity of Glycoluril-Mediated Claisen-Like Condensations Harrison P.H.M, Kam K., Chen M.
17:00 00359 Investigating Rebeccamycin Biosynthesis. Development of Directed ortho and Remote Metalations / Cross-Coupling Strategies for the Synthesis of Bioactive Molecules Groom K., Snieckus V., Zechel D.L.
17:00 00360 Development and Evaluation of New Chiral Catalysts for Olefin Metathesis Fournier P.-A., Collins S.K.
17:00 00361 Using the McMurry Reaction to Synthesize Ligands Based on a Tetraarylethylene Framework Fancy P.D., Chung M.K., Stryker J.M.
17:00 00362 Indium (III) Catalyzed Friedel-Crafts Hydroxyalkylation of Mucohalic Acids: A Green and Efficient Procedure for Highly Functionalized c-Aryl c-Butenolides Zhang J., Blazecka P.G., Curran T.T.
17:00 00363 Ring-Closing Metathesis and Direct Arylation Reactions en route to Functionalized Higher Helicenes Vachon M.P., Grandbois A., Collins S.K.
17:00 00364 Progress Towards an Asymmetric Preparation of Helicenes Grandbois A., Fournier P.-A., Collins S.K.
17:00 00365 Green Catalytic Oxidations of Alcohols to Carbonyl Compounds by Oxygen under Solvent-Free and Transition-Metal-Free Conditions Herrerias C.I., Zhang T.Y., Li C.-J.
17:00 00366 Disparate Reactivity of Grignard Reagents in Molecular and Ionic Solvents Taylor S.A., Ramnial T., Clyburne J.A.C., Walsby C.J.
17:00 00367 Synthesis and Applications of DABCO-Based Ionic Liquids Wykes A., MacNeil* S.
17:00 00368 Using Electrochemistry for the Synthesis of Unnatural Sequence-Defined Oligomers Chesneau F.F.R.M., Sweeney M.D., Vocadlo D.J.
17:00 00369 Polypyrroles as Radical-Trapping Antioxidants. Distinguishing Hydrogen-Atom Transfer (HAT) and Single Electron Transfer (SET) Pathways MacLean P.D.
17:00 00371 Regio- and Stereoselectivity of the 1,3-Dipolar Cycloaddition of Cyclopropanes and Nitrones: A Theoretical Study Wanapun D., Kerr M.A., Woo T.K.
17:00 00372 Photoinduced Intramolecular Electron Transfer in Tethered Ru(bpy)3-Toluidine Systems Schepp N.P., Lee F.
17:00 00373 An Unusual Dienone-Phenol Rearrangement and Formation of a Quinhydrone Complex Alarcon I.Q., Nelson K.M., Quail J.W., Abrams S.R.
17:00 00374 Sulfur Ylide Epoxidations: A Mechanistic Investigation Montoya-Peleaz P.J., Edwards D., Crudden C.M.
17:00 00375 On the Interplay of Weak Interactions in RNSO.Pyridine Complexes Li S., Ivanova E.V., Muchall H.M.
17:00 00376 Mediation of Photoisomerization and Photodimerization Reactions by Cucurbit[7]uril and Cucubit[8]uril in Aqueous Solution Macartney D.H., Wang R., Yuan L., Hettiarachchi D.S.
17:00 00377 Excited State Intramolecular Redox Reactions of Anthraquinone System and Applications as a Photoremovable Protecting Group Hou Y.Y., Wan P.
17:00 00378 Insight into the Kinetics and Regioselectivity of the Hydroboration of Vinyl Arenes with Pinacolborane Catalyzed by Iridium Complexes Hleba Y.B., Crudden C.M.
17:00 00379 Pathways of Decomposition of the Insecticide, Diazinon, in Moderately Acidic Sulfuric Acid Media. Excess Acidity Analysis Dust J.M., Churchill D.C., vanLoon G.W., Buncel E.
17:00 00380 Laser Flash Photolysis of Aryl(halo)- and Pyridyl(halo)carbenes in Y Zeolites: The Role of Zeolite Encapsulation on Carbenic Stability and Reactivity Moya-Barrios R., Cozens F.L.
17:00 00381 Photoregulated Liposomes: The Effect of Spirooxazine Structure on Membrane Permeability Louis K.M., Murphy R.S.
17:00 00382 Mechanistic Studies on the Effects of Bulky Groups on Allene Oxide Stability Konecny M., Schepp N.P.
17:00 00383 Selective Modification of Monolayer-Protected Gold Nanoparticles via the Photo-Wolff Rearrangement Johnson M.B., Workentin* M.S.
17:00 00384 Mechanistic Studies of the Reactions of Diarylgermylenes and Tetraaryldigermenes in Solution Huck L.A., Leigh W.J.
17:00 00385 Autoxidation of 1-Naphthol-Formaldehyde Polymer in Alkaline Aqueous Solution Esmaeili N., Nazari K., Kameli M., Mohajerani B.
17:00 00386 Photodecarboxylation of Xanthone Acetic Acids: C-C Bond Heterolysis from the Singlet Excited State Blake J.A., Lukeman M., Scaiano J.C.
17:00 00387 The Photochemistry of a Potential Precursor to GeH2 and Ge2H4 in Solution Billone P.S., Harrington C.R., Beleznay K., Leigh W.J.
17:00 00388 Comparative Chemical and Electrochemical Oxidation of Dihydroxybenzoic Acids in the Presence of Arylsulfinic Acids: Diversity in the Electroorganic and Organic Synthesis of Diaryl Sulfones Alizadeh A., Nematollahi D., Habibi D., Hesari M.
17:00 00389 Synthesis and Application of Sugar-Lysine Chimera Zhang K., Sun Z., Nguyen D., Schweizer F.
17:00 00390 Efficient Synthesis of Hydroxyethylene Dipeptide Isosteres of Phe-Aib and Ala-Aib Genest N., Lama T., Lubell W.D.
17:00 00391 Synthesis of Pi-Excessive and Pi-Deficient Phenylalanine Derivatives from a Common 1,4-Diketone Intermediate Dorr A.A., Lubell W.D.
17:00 00392 Development of New Chiral Ligands for Asymmetric Synthesis Boudreault P.L., Voyer N.
17:00 00393 Synthesis of Macrocyclic Peptides: Toward Larger Nanopores Blanchette J.P., Ferland P., Voyer N.

Monday AM

OR4CC-Mariner 5

Macromolecular and Supramolecular Chemistry (Joint with IN and MS) (joint with IN3)

Organizer(s) - Bruce Grindley
Chair(s) - Laurence Thompson

08:00 Joint with Inorganic Chemistry and Macromolecular Science and Engineering Divisions - See IN3

10:00 Pure or Applied Inorganic Chemistry Award Lecture presented by Heinz-Bernhard Kraatz

11:00 End of Session


REMINDER
11:00 Alfred Bader Award Lecture presented by Mark Lautens in CC-Port Royal C1

OR8CC-Mariner 4

Organic Reaction Mechanisms

Organizer(s) - James Pincock and Frances Cozens
Chair(s) - Frances Cozens

08:20 00497 Hydroxide-Dependent Breakdown of Carbinolamides: A Non-Linear Hammett Correlation for N-(Hydroxymethyl)benzamide Derivatives Nagorski R.W.
08:40 00498 Ultrafast Study of Azide and Diazo Excited States and of the Nitrenes and Carbenes they Produce Platz‡ M., Gustafson T., Burdzinski G., Hadad C., Hackett J., Wang J.
09:20 00499 Photogeneration of Enol Radical Cations in Solution Schepp N.P., Rodriguez-Evora Y.
09:40 Coffee Break
10:00 00500 Interaction of Semiconductor Quantum Dots with Organic Free Radicals Scaiano J.C., Laferrière M., Maurel V., Galian R.E., Billone P.
10:20 00501 Crystal Engineering the Covalent Bond via Principles of Supramolecular Chemistry MacGillivray‡ L.R., Friscic T., Papaefstathiou G.S., Chu Q., Georgiev I.G., Hamilton T.D.
11:00 End of Session


REMINDER
11:00 Alfred Bader Award Lecture presented by Mark Lautens in CC-Port Royal C1

OR9CC-Highland 10

Peptide Science (Joint with BM) (joint with BM9)

Organizer(s) - William Lubell
Chair(s) - William Lubell

08:00 Joint with Biological and Medicinal Chemistry Division - See BM9


REMINDER
11:00 Alfred Bader Award Lecture presented by Mark Lautens in CC-Port Royal C1

OR10CC-Port Royal C1

Recent Advances in Organic Synthesis

Organizer(s) - Jean Burnell and Ian Pottie
Chair(s) - Ian Pottie

08:00 00502 A Homo 3+2 Cycloaddition Approach towards Nakadomarin A Young I.S, Kerr M.A.
08:20 00503 Progress towards a Total Synthesis of Palau'amine Cernak T.A., Gleason J.L.
08:40 00504 2p, 4p and 6p Electrocyclic Processes for the Construction of Polycyclic Products West‡ F.G.
09:20 00505 A New Original Process for the Synthesis of Protected Anilines via Curtius Rearrangement Leogane O., Lebel H.
09:40 Coffee Break
10:00 00506 Asymmetric Synthesis of All-Carbon Benzylic Quaternary Stereocenters via Cu-Catalyzed Conjugate Addition of Dialkylzinc Reagents to 5-(1-Arylalkylidene) Meldrum's Acids Fillion E., Wilsily A.
10:20 00507 Synthesis of the Left-Hand Cyclopropa[c]pyrrolo[3,2-e]indol-4-one (CPI) Subunit of CC-1065 Ganton M.D., Kerr M.A.
10:40 00508 Developing New Methods to Access Helically Chiral Molecules via Transition Metal Catalysis Collins S.K., Vachon M.P., Grandbois A., Fournier P.-A.
Alfred Bader Award Lecture presented by Mark Lautens

Introduction of Mark Lautens by André Charette

11:00 00509 Meddling with Metals: New Reactions and Applications Lautens‡ M.
11:40 End of Session


Monday PM

OR2CC-Mariner 5

Heterocycles and Heteroatom-Containing Rings

Organizer(s) - Alison Thompson
Chair(s) - Richard Manderville

13:00 00679 Inverse Electron Demand Diels-Alder (IEDDA) Reactions of Coumarin-Fused 2-Azadienes Kudale A.A., Bodwell* G.J.
13:20 00680 Studies in Catalytic Direct Arylation of Pyridine N-Oxides Campeau L.-C., Fagnou K.
13:40 00681 Application of the Rhodium-Catalyzed Methylenation Reaction: Total Synthesis of Desoxygaliellalactone Parmentier M., Lebel H.
14:00 00682 Quest for Diatomic Selenium Rys A.Z., Schultz E.K.V., Harpp D.N.
14:20 00683 Reduction of Substituted Phenanthrolines as a Route to Chiral Benzimidazolylidenes Metallinos C., Barrett F.B., Wang Y., Zaifman J.
14:40 00684 Recent Advances in the Stereoselective Synthesis of Dipyrromethene Complexes Thompson A., Al-Sheikh-Ali A., Beshara C.S., Wood T.E.
15:00 Coffee Break
15:20 00685 Biosynthesis of Pyrrolic Natural Products Leeper‡ F.J.
16:00 00686 The Total Synthesis of Phyllantidine Carson C.A., Kerr M.A.
16:20 00687 Transmembrane Ion Transporters Based on Heterocycles Davis‡ J.T., Seganish J., Kaucher M.
17:00 End of Session

OR3CC-Mariner 4

Innovative Chemistry in Novel Media

Organizer(s) - Robert Singer
Chair(s) - Robert Singer

13:00 00688 Switchable Solvents and Surfactants Jessop‡ P.G., Eckert C.A., Liotta C.L.
13:40 00689 Applications of Phosphonium Salt Ionic Liquids in Organic Synthesis McNulty‡ J., Larichev V., Nair J.
14:00 00690 Solid-State Synthesis of Imides via Mechanochemistry Cheney M.L., Zaworotko M.J.
14:20 00691 In-Situ Preparation of Catalytic Palladium Nanoparticle/Silica Composites in Supercritical Carbon Dioxide Kerton F.M., Saffarzadeh-Matin S., Rayner C.M., Lynam J.M.
14:40 Coffee Break
15:20 00692 Quasi-Nature Organic Chemistry: Developing Metal-Mediated and Catalyzed Reactions in Air and Water Li‡ C.-J.
16:00 00693 Efficient Trost's c- Addition Catalyzed By Reusable Polymer-Supported Triphenylphosphine in Aqueous Media Skouta R., Varma R.S., Li C.-.J.
16:20 00694 Switch-Hitting Behaviour for Grignard Reagents in Molecular and Ionic Solvents Walsby C.J., Taylor S.A., Ramnial T., Clyburne J.A.C.
16:40 End of Session

OR6CC-Highland 8

NMR of Biological Molecules (Joint with BM and PT)

Organizer(s) - David Jakeman
Chair(s) - David Jakeman

13:00 Joint with Biological and Medicinal Chemistry and Physical Chemistry Divisions - See BM8

16:40 End of Session

OR10CC-Port Royal C1

Recent Advances in Organic Synthesis

Organizer(s) - Jean Burnell and Ian Pottie
Chair(s) - Brian Keay

13:00 00695 A Pauson-Khand Annulation, Ring-Expansion Approach to the [9.5.5] Carbocyclic Skeleton of Aquariolide A Thornton P.D., Burnell D.J.
13:20 00696 A Quadruple Diene-Transmissive Diels-Alder Cycloaddition Approach to Quassinoids Perreault S., Spino* C.
13:40 00697 Cobalt-Mediated [5+2] Cycloaddition Reactions: A New Reactivity Pattern for Seven-Membered Ring Synthesis Stryker J.M., Witherell R., Ylijoki K., Kirk A.D.
14:00 00698 Catalytic Electromediated Transformations of Cation and Anion Radicals Little‡ R.D., Park Y.S., Graham J.
14:40 00699 5,5-Dicyanocyclopentadiene as a Precursor to Synthons for Tandem Anionic Reaction Sequences to Polycyclic Natural Products: DIscovery of a Very Facile Allenolate Cope Reaction Krismanich A., Dmitrienko G.I.
15:00 Coffee Break
15:20 00700 Regioselective Synthesis of Vinyl Sulfides Using Rhodium-Catalyzed Alkyne Hydrothiolation Love J.A.
15:40 00701 A Stereochemically Versatile Route to Hexapropionates Ward‡ D.E.
16:20 00702 The Pseudo-Nazarov Reaction: gem-Dihalocyclopropanes as Novel Substrates for the Nazarov Cyclization Grant T.N., West F.G.
16:40 00703 Catalytic Enantioselective Reduction of b,b-Disubstituted Nitroalkenes Using a Bisphosphine Monoxide Desrosiers J.-N., Charette A.B.
17:00 End of Session

ORPCC-Port Royal D,E

Posters

Organizer(s) - Bruce Grindley
Chair(s) - Bruce Grindley

From 17:00 until 19:00

17:00 00704 Towards the Synthesis of Lysergic Acid via a Directed ortho Metalation (DoM) Strategy Zhao Y., Snieckus V., Larkin A.
17:00 00705 Progress Towards a Total Synthesis of Longithorone C Zakarian J., El-Azizi Y., Collins S.K.
17:00 00706 Tetraarylphosphonium Salt: Supported TEMPO Catalyst and (Diacetoxyiodo)benzene Reagent Roy M.-N., Charette A.B.
17:00 00707 Synthesis of Crown Ethers by Simultaneous Double Directed Benzylic Lithiation of a Biphenyl Substituted with Tertiary Amide Groups Reed J.N., Mora-Diez N., Key J., Mahboob A.
17:00 00708 Synthetic Efforts Towards the Synthesis of 3,3'-Disubstituted MeO-BIPHEP Derivatives Incorporating the "3,5-Dialkyl Meta Effect" Rankic D.A., Keay B.A.
17:00 00709 Towards the Total Syntheses of Majusculoic Acid and (-)-Perhydrohistrionicotoxin Philippe J., Charette A.B.
17:00 00710 Catalytic Enantioselective Aldol Reaction as a Tool for Natural Products Synthesis Niewczas I.S., Palyam N., Majewski M.
17:00 00711 The First Highly Efficient and "Multi-Component" Synthesis of b-Lactams from N-Substituted Hydroxylamine, Aldehydes, and Alkyne Zhao L., Li C.-J.
17:00 00712 Diels-Alder Reactions of Boron Containing Aromatic Compounds Wood T.K., Piers W.E.
17:00 00713 Design, Synthesis and Development of Prodigiosin Analogues for Breast Cancer Chemotherapy Regourd J., Thompson A.
17:00 00714 Syntheses of Sydnone Derivatives via NO Reactions Perepichka I., Bohle D.S., McQuade L.
17:00 00715 Synthesis of Propargyl Amines via Asymmetric Cross-Dehydrogenative Coupling (CDC) Reactions MacLeod P.D., Li Z., Li C.-J.
17:00 00716 Synthesis of 4-Amino-2,2'-bipyrroles as Building Blocks to Prepare Analogs of Natural Products Jolicoeur B., Lubell W.D.
17:00 00717 A Novel Approach to Xanthones Using an Inverse Electron Demand Diels-Alder (IEDDA) Driven Domino Reaction Dang A.T., Bodwell G.J.
17:00 00718 Attempts at Complexation Between Dipyrrinones and Boron Trifluoride in an Effort to Mimic BODIPY-Type Structures Chapman E., Thompson A.
17:00 00719 General Synthetic Route to Chiral Lactams: A New Approach Buranov A.U.
17:00 00720 Synthesis of N-Containing Heterocycles by Enantioselective Catalytic Addition of Diorganozinc Reagents on Imines Bonnaventure I., Charette A.B.
17:00 00721 Increased Dioxathiazinane Reactivity by Solvation Stabilization of a Twisted Boat Conformation Blankenship J.W., Galaud F., Lubell W.D.
17:00 00722 Dipyrromethenes Containing a Stereocenter: Does Simple Diastereoselectivity Occur upon Complexation with a Metal (II) Ion? Beshara C.S., Thompson A.
17:00 00723 Prins Cyclization under Mild Conditions: Formation of Cyclic Ethers from Unsaturated alpha-Haloether Arpin P., Spino C., Hill B.
17:00 00724 Highly Diastereoselective Templated Complexation of Dipyrromethenes Al-Sheikh Ali A., Thompson A.
17:00 00725 Delineating Binding and Linker Residues in Extended CRIB Polypeptides for High-Affinity Interactions with Cdc42 by use of NMR Spectroscopy and Fluorescence Binding Studies Mayele M., Su Z.D., Osborne M.J., Xu X., Xu P., Ni F.
17:00 00726 Isolation and Structural Characterization of Polysaccharides from the Green Microalgae Chlorella Pyreinoidosa. Effect of Molecular Weight on Immunostimulatory Effects Reyes Suárez E., Kralovec J.A., Barrow C.A., Ewart H.S., Syvitski R., Lumsden M.D., Grossert J.S., Volmer D.A., Grindley T.B.
17:00 00727 Advances in the Synthesis and Applications of N-Alkenyl Aziridines Yu L., Blyumin E., Yudin A.K.
17:00 00728 Progress Toward the Synthesis of Traversianal Song D., West F.G.
17:00 00729 New Tandem Ruthenium-Catalyzed Olefin Metathesis/Oxidation Reactions Scholte A.A., Snapper M.L.
17:00 00730 An Investigation on the Formation and Reactivity of Borodicyclohexyl Methylenenitronate with Various Aldehydes Carneiro K.M.M., MacDonald F.K., Pottie I.R.
17:00 00731 Organocatalytic Asymmetric Michael Addition of Cyclic Ketones to Nitro-Olefins Pansare S.V., Pandya K.
17:00 00732 Stille Coupling of Stereochemically Defined a-Alkoxybenzylstannanes Nguyen M.T., Chong J.M.
17:00 00733 The Application of Manganese (III) Acetate Oxidative Radical Cyclizations to the Synthesis of Indole and Pyrrole Containing Natural Products Magolan J., Kerr M.A.
17:00 00734 Palladium Catalysed Cross Coupling Reactions of Diazine N-Oxides Leclerc J.-P., Fagnou K.
17:00 00735 A Diels-Alder Approach towards the Clausamines Lebold T.P., Kerr M.A.
17:00 00736 Direct Arylation in the Synthesis of (R)-Nuciferine and its Analogues Lafrance M., Blaquiere N., Fagnou K.
17:00 00737 An Iterative Approach to the Total Synthesis of Ionomycin Joly M.-A., Allan M., Gund V., Spino* C.
17:00 00738 Reversal of Product Absolute Configuration and Applications Using 3,3'-Disubstituted BINAP Ligands Hopkins J.M., Keay B.A.
17:00 00739 The Use of Fluorous Chiral Supports in the Oxidative Coupling of a-Amino Acids to Stereoselectively Generate Quaternary Carbon Centres Geary L.M., Hultin P.G.
17:00 00740 Progress Towards the Total Synthesis of (-)-Aspidofractinine Gagnon D., Spino C.
17:00 00741 Syntheses and Applications of Stannyl Butadienes Darwish A., Chong J.M.
17:00 00742 Nitrile-Mediated Hydrogen-Deuterium Exchange and the Synthesis of Specifically Labelled b- and c-Amino Acids Cook M.C., White R.L.
17:00 00743 Stereoselective Approaches to Spiroketal Scaffolds and Norstatine-Type Peptide Isosteres Pansare S.V., Adsool V.A., Dhudshia B.
17:00 00744 The Comparison Between the Oxidation of Organic Compounds in Convenient and Microwave Conditions by Tetramethylammonium Fluorochromate (TMAFC) Mohammadi M.K., Jangjoo A.
17:00 00745 Synthesis of 2-Amino-2-chromenes in Aqueous Media by Na/PN Mezdar A., El makssoudi A., Zahouily M., Rayadh A., Sebti S.
17:00 00746 On Using Tree Analysis to Quantify the Material, Input Energy, and Raw Material Cost Throughput Efficiencies of Simple and Complex Synthesis Plans and Networks Andraos J.
17:00 00747 Diastereoselective Arylithium Addition to an a-Trifluoromethyl Imine. Practical Synthesis of a Potent Cathepsin K Inhibitor Roy A., Gosselin F., O'Shea P.D., Chen C.-Y.

Tuesday AM

OR4CC-Mariner 5

Macromolecular and Supramolecular Chemistry (Joint with IN and MS) (joint with IN3)

Organizer(s) - Bruce Grindley
Chair(s) - Steve Loeb

08:20 Joint with Inorganic Chemistry and Macromolecular Science and Engineering Divisions - See IN3

11:20 End of Session


REMINDER
11:25 CIC Medal Lecture presented by Ronald Kluger in CC-Port Royal C1

OR6CC-Highland 8

NMR of Biological Molecules (Joint with BM and PT)

Organizer(s) - David Jakeman
Chair(s) - David Jakeman

08:20 Joint with Biological and Medicinal Chemistry and Physical Chemistry Divisions - See BM8

11:20 End of Session


REMINDER
11:25 CIC Medal Lecture presented by Ronald Kluger in CC-Port Royal C1

OR8CC-Mariner 4

Organic Reaction Mechanisms

Organizer(s) - James Pincock and Frances Cozens
Chair(s) - Matt Lukeman

08:40 00904 The p-Hydroxyphenacyl Chromophore: An Efficient, Highly Versatile Platform for Photoremoveable Protecting Groups Givens‡ R., Stensrud K., Cope E., Senadheera S., Perera C., Yousef A., Ma C, Yang S.
09:20 00905 Intramolecular Charge-Transfer Excited States in the Photochemistry of Methoxy-Substituted Stilbene Derivatives Roberts J.C., DeCosta D.P., Pincock A.L., Pincock J.A.
09:40 Coffee Break
10:00 00906 Mechanistic Aspects of the Formation of Iminoxyl Radicals and Nitriles in the Photosensitized Reactions of Aldoximes Hsu S., Hunter J.W., Marquez B.V., Rangel N.A., Sanguantrakun N., de Lijser H.J.P.
10:20 00907 Nanosecond Time-Resolved IR Studies of Carbonyl Nitrenes Toscano‡ J.P.
11:00 00908 Influence of Alkali Metal Cation on the Distance of Electron Migration in Zeolite Y Cozens F.L., Keirstead A.E.
11:20 End of Session


REMINDER
11:25 CIC Medal Lecture presented by Ronald Kluger in CC-Port Royal C1

OR10CC-Port Royal C1

Recent Advances in Organic Synthesis

Organizer(s) - Jean Burnell and Ian Pottie
Chair(s) - David MaGee

08:00 00909 Asymmetric Allylboration of Cyclic Imines Using 3,3'-Disubstitutedbinaphthol-Modified Boronates and an Enantioselective Synthesis of (-)-Corynantheidol Wu T.R., Chong J.M.
08:20 00910 Stereoselective Construction of Quaternary Centers Employing a Radical-Based Reaction from Acyclic Precursors Cardinal-David B., Duplessis M., Guindon Y.
08:40 00911 Natural Product Synthesis Clive‡ D.L.J.
09:20 00912 In-Situ Generated Iodonium Ylides: Carbene Transfer, the Formation of Cyclic Ylides, and Their Subsequent Rearrangements Murphy G.K., West F.G.
09:40 Coffee Break
10:00 00913 Catalytic Enantioselective and Catalyst-Controlled Diastereofacial-Selective Additions of Allyl- and Crotylboronates to Aldehydes Promoted by Chiral Brønsted Acid Rauniyar V., Hall D.G.
10:20 00914 Synthesis of Biologically Active Natural Products Snider‡ B.B.
11:00 00915 New Direct Arylation Reactions for the Synthesis of Biaryl Molecules Fagnou K.
11:20 End of Session


REMINDER
11:25 CIC Medal Lecture presented by Ronald Kluger in CC-Port Royal C1


Tuesday PM

OR1CC-Port Royal C1

Carbohydrates and Drug Discovery (Joint with BM) (joint with BM2)

Organizer(s) - Bruce Grindley
Chair(s) - France-Isabelle Auzanneau

13:40 Joint with Biological and Medicinal Chemistry Division - See BM2

16:40 End of Session

OR2CC-Mariner 5

Heterocycles and Heteroatom-Containing Rings

Organizer(s) - Alison Thompson
Chair(s) - Alison Thompson

13:40 01063 Oligopyrrole Anion Receptors: Simple Models for Prodigiosins? Sessler‡ J.L., Gale P.A., Naumovski L., Moyer B.A., Marquez M., Bucher C., Cho W.-S., Cho D.-G., Deqiang A., Gross D.E., Eller L.R., Wang Z., Magda D.M.
14:20 01064 Application of 15N NMR Spectroscopy to Studies of Dipyrromethene Metal Complexes Wood T.E., Thompson A., Berno B.
14:40 01065 Aminoprodigiosin Synthesis Jolicoeur B., Lubell W.D.
15:00 Coffee Break
15:20 01066 Oxidation of Prodigiosins and Potential Relevance to Cytotoxicity Manderville‡ R.A.
16:00 01067 Amidopyrroles: From Anion Receptors to Membrane Transport Agents Gale‡ P.A.
16:40 End of Session

OR5CC-Mariner 4

Natural Products (Joint with BM) (joint with BM7)

Organizer(s) - Paul Harrison
Chair(s) - Paul Harrison

ISOLATION AND BIOSYNTHESIS

13:40 Joint with Biological and Medicinal Chemistry Division - See BM7

16:40 End of Session

OR7CC-Mariner 1

Organic Materials for Optical, Electronic or Photonic Applications (Joint with MS and MT) (joint with MS5)

Organizer(s) - Wayne Wang and Tim Bender
Chair(s) - Harald Stöver, Neil Branda

13:40 Joint with Macromolecular Science and Engineering and Materials Chemistry Divisions - See MS5

13:40 The Macromolecular Science and Engineering Award Lecture presented by Wayne Wang

16:40 End of Session

OR8DH-Baronet 6

Organic Reaction Mechanisms

Organizer(s) - James Pincock and Frances Cozens
Chair(s) - James Pincock

13:40 01068 Comparison of N-Sulfinylamine and Isocyanate Hydrolysis: A Computational Study Ivanova E.V., Muchall H.M.
14:00 01069 Solvent Effects on Aliphatic Nucleophilic Substitution: A Computational Study of Isotope Effects in Solvolysis Larsson P.-E., Williams I.H.
14:20 01070 Mechanistic Study of a Novel Ring Contraction of Lactams Drouin A., Spino C., Lessard J.
14:40 01071 The Direct Detection and Kinetic Studies of Dimethylgermylene and its Dimer Tetramethyldigermene by Laser Fflash Photolysis in Solution Lollmahomed F.B., Harrington C.R., Leigh W.J.
15:00 Coffee Break
15:20 01072 The Reactivity of Diarylmethyl Carbocations in Non-Protic Zeolites Hallett-Tapley G.L., McWhinney R.D., Cozens F.L.
15:40 01073 Intramolecular Photoredox Chemistry of Substituted Benzophenones: The Effect of Phenyl Substituents Mitchell D., Basaric N., Wan P.
16:00 01074 Temperature and Solvent Effects, Rate Constants and Activation Parameters for the Processes of the Excited States of Substituted Benzenes Gonzalez C.M., Pincock J.A.
16:20 01075 Towards the Mechanism of Action and the Development of Fluorescent Sensors for Reactive Oxygen Species Heyne B., Scaiano J.C.
16:40 End of Session

ORPCC-Port Royal D,E

Posters

Organizer(s) - Bruce Grindley
Chair(s) - Bruce Grindley

From 16:40 until 18:40

16:40 01076 Synthesis and Conformational Analysis of Fused Sugar-Proline Hybrids Owens N., Schweizer F.
16:40 01077 Investigation into the Importance of Sidechain Length and Functionality in C-Linked Antifreeze Glycoproteins Tam R.Y., Ben R.N.
16:40 01078 Synthesis and SAR of Potent Aggrecanase-1 Inhibitors: The Sulfonamide Series How D., Sabatini J., Hopper D., Vera M., Laakso L., Xiang J., Hu F., Cunningham K., Moysak L., Skotnicki J., Tam S., Morris E., Mansour T., Georgiadis K., Sum P.E.
16:40 01079 Preparation and Evaluation of a C-Linked AFGP Analogue Containing a geminal-Difluoromethylene Group Chaytor J.L., Ben R.N.
16:40 01080 2,3-Difluoro Sialic Acid Derivatives as Potential Inhibitors of Trypanosoma cruzi Trans-Sialidase and Influenza Virus Sialidase Buchini S., Watts A.G., Withers S.G.
16:40 01081 Synthesis and Characterization of Fullerene-Endcapped Cruciform Conjugated Oligomers Zhou N., Zhao Y.
16:40 01082 Syntheses, 1H NMR and Photochromic Properties of Modified Dimethyldihydropyrenes Zhang R., Berg D.J., Mitchell R.H.
16:40 01083 A Facile "One-Pot" Click Method to Assemble Dendritic Molecules to C60 Fullerene Mahmud I., Zhao Y.
16:40 01084 Application of Polyurethane in Producing Some Microencapsulated Solid and Liquid Pesticides Kassiri M., Ahmadi A.
16:40 01085 Towards a New LC Material by a Combined Metalation-Cross Coupling Route Gan W., Snieckus V., Lemieux R.P.
16:40 01086 Structure and Activity of Polar Metabolites Produced in Leaves of Brassica Species Zheng Q.-A., Gadagi R., Pedras M.S.C.
16:40 01087 Differential Production of Phytoalexins in Leaves of Brassicas in Response to the Biotrophic Fungus Albugo candida and Copper Chloride Pedras M.S.C., Zheng Q.-A., Gadagi R., Adio A.M., Rimmer S.R.
16:40 01088 Analysis of Indole Phytoalexins from Crucifers by HPLC-DAD-ESI-MS/MS Pedras M.S.C., Adio A.M., Suchy M., Zheng Q.-A., Okinyo D.P.O., Sarwar M.G., Jha M.
16:40 01089 Preparation of Postulated Intermediates of the Biosynthetic Transformation of Vitamin B6 into the Pyrimidine Unit of Vitamin B1 Goncharenko M., Spenser I.D.
16:40 01090 Progress Toward the Total Synthesis of the Bisbenzyltetrahydroisoquinoline Alkaloid (-) Cycleanine Dakhil O.O., Georghiou P.E.
16:40 01091 The Biological Activity of Pramanicin, and Structure-Activity Relationships Harrison P.H.M., Simayi T., Ferras J.
16:40 01092 A Simple Biomimetic Synthetic Approach to the D Ring of the Kinamycin Antibiotics: Insights into the Conformation of Kinamycin F Chen N., Carriere M.B., Laufer R.S., Taylor N.J., Dmitrienko G.I.
16:40 01093 Natural Products of Commercial Interest from Rubber-Bearing Plants of Central Asia Buranov A.U.
16:40 01094 Phytochemical Studies on Pagiantha dichotoma Zhang Y., Kalhari K.S., Ata A.
16:40 01095 Alternative Commercial Sources of Natural Rubber Scholte A.A., Bushman B.S., Vederas J.C.
16:40 01096 Glucosinolate Profile of Spectacle Pod (Dithyrea wislizenii) Fruits Montaut S., Li R., Iori R., Barillari J., Rollin P.
16:40 01097 Cloning of a Moss Chalcone Synthase and Evolution of the Chalcone Synthase Superfamily Jiang C., Schommer C.K., Suh D.-Y.
16:40 01098 New Bioactive Chemical Constituents of Coprinus micaceus Haq S., Ata A.
16:40 01099 Bioactive Natural Products from Barleria priontis Kalhari K.S., Ata A., Samamrasakara R.
16:40 01100 Chemical and Biochemical Behaviour of the Kinamycin Antibiotics: In Search of a Mode-of-Action Abbott G.L., Goodfellow V., Heynen M., Adedayo O., Taylor N.J., Dmitrienko G.I.
16:40 01101 Photoswitchable Electrical Conductivity Based on the Dimethyldihydropyrene Photoswitch Robinson S.G, Mitchell R.H.
16:40 01102 The Synthesis and Electronics of Two Classes of Annelated Delocalized Stable Organic Radicals with Complementary Redox Processes: Benzonitronyl Nitroxides and Bis-Thiadiazinyl Radicals Dooley B.M., Frank N.L.
16:40 01103 Synthesis of Oligomer-exTTF Bridged Bisfullerene Polyads Chen G., Zhao Y.
16:40 01104 Narrow-Rim Functionalized Calix[4]arenes Produced via Sonogashira Coupling: Their Potential NLO Properties and Photochemical Reactions Al-Saraierh H., Georghiou P.E.
16:40 01105 Synthesis of New 2,7-Carbazolenevinylene-Based Copolymers and Characterization of their Photovoltaic Properties Michaud A., Leclerc N., Leclerc M.
16:40 01106 Synthesis and Characterization of High Purity Polymers for Organic Light Emitting Diode (OLED) Applications McFarlane S., Veinot J.G.C.
16:40 01107 Interactions of Self-Trapped Beams of Incoherent White Light Kasala K., Sakalauskas M., Saravanamuttu K.
16:40 01108 Estimation of Volume Fraction and Geometric Tortuosity in a Porous Polymer by Advanced Quantitative Image Analysis Using Mathlab Kamaludeen M., Matchett A., Doan H.
16:40 01109 Surface Coating with Mesomorphic Polyionic Discotic Liquid Crystals Based on Tetraazaporphyrins and Phthalocyanines Eichhorn S.H., Dufour S.
16:40 01110 Studies on the Supramolecular Complexation of [60]Fullerene with Calixnaphthalenes and some other Macrocyclic Hosts Tran A.H., Georghiou P.E., Thompson D.W.
16:40 01111 Design, Synthesis and Liquid Crystal Studies of [2]Rotaxanes Suhan N., Loeb S.J.
16:40 01112 Cyclodextrin-Based Polymeric Sensor for Nitro-Aromatics Evans C.H., Zohrehvand S., Katic S.
16:40 01113 Selective Modifications of Chitosan: Solubility Enhancement and Regioselective Protections Gagnon J.
16:40 01114 Acid-Base Driven Molecular Shuttles from Rotaxanes and Catenanes Loeb S.J., Tiburcio J., Vella S.J.
16:40 01115 Copolymerization Studies of Polar Monomers with Propylene: Monomer Synthesis and Polymerization Studies Stojcevic G., Baird M.C.
16:40 01116 Anhydride Functionalized Polydivinylbenzene Structured Microspheres Srivastava M., Stover H.D.H
16:40 01117 Factors Responsible for Accessibility of the Cavity in Amphiphilic Calix[4]arenes Pojarova M., Ananchenko G.S., Udachin K.A., Ripmeester J.A., Perret F., Coleman A.W.
16:40 01118 Molecule-Responsive Block Copolymer Self-Assembly Ishihara Y., Bazzi H.S., Toader V., Sleiman H.F.
16:40 01119 Molecular Tectons with Pyrogallol "Sticky Sites" Hamilton T.D., Wuest J.D.
16:40 01120 Physical Characterization of Blends of Poly(D-lactide) and LHRH (a Leuprolide Decapeptide Analog) Fraschini C., Jalabert M., Prud'homme R.E.
16:40 01121 Use of Metal Coordination to Direct Supramolecular Assembly Duong A., Wuest J.D.
16:40 01122 Guest Removal and Insertion in a Tripodal Host-Guest Framework Burchell T.J., Sidhu P.S., Enright G.D., Ripmeester J.A.
16:40 01123 Chitosan Asymmetric Chelating Polyligands Synthesis: Regioselective O-6 Silylation on N-Phthaloyl Chitosan and on a New Organosoluble Chitosan Salt Binette A., Gagnon J.
16:40 01124 The Synthesis of Novel Glycoluril-Based Dimer Macrocycles Bridged by Diamines as Molecular Hosts Wyman I.W., Macartney D.H.
16:40 01125 Macrocyclic Derivatives of Glucosamine and Chitosan Miller K.J., Haines R.I.
16:40 01126 New Rotaxane Linkers for Metal Organic Rotaxane Frameworks (MORFs) Mercer D.J., Loeb S.J.
16:40 01127 Selective Sorption of Lewis Bases by a Weakly Bonded Coordination Solid May L.J., Shimizu G.K., Hamaed H., Schurko R.W.
16:40 01128 The Design of a Proton Conducting Metal-Organic Material Hurd J.A., Sander M.J., Shimizu G.K.
16:40 01129 Crystal Engineering of Porous Hydrogen Bonded Networks Dalrymple S.A., Shimizu G.K.
16:40 01130 Supramolecular Assemblies of Telluradiazoles Cozzolino A.F., Vargas-Baca I.
16:40 01131 Second-Sphere Coordination as a Template in the Self-Assembly of [2]Catenanes Blight B.A., Wisner J.A.
16:40 01132 A Study of the Zirconium-Polymeryl Species Formed during Propylene Polymerization by Metallocene and Nonmetallocene Catalysts Vatamanu M., Baird M.C.
16:40 01133 Annelated Radicals for Magneto-Conducting Materials: The Synthesis and Properties of Azo-Substituted Benzotriazinyl Radicals Zsombor M.S., Frank N.L.
16:40 01134 Development of p-Donor/Acceptor Oligomers as Tuneable HOMO/LUMO Gap Materials Wisner J.A., Yost C.M.
16:40 01135 Lowering the Bandgap of Polydiimines Mason R.J., MacLean B.J.
16:40 01136 a-Only Substituted Push-Pull Oligothiophenes Containing a Halogen and a Nitro Group - Synthesis and Spectroscopic Characterisation Sears W.A., Johnson M.J., Winter A.J., MacKinnon C.D., Sears W.M.
16:40 01137 New Organic Redox Couples Based on Phosphorus Ylides Suitable for Electrochemical Photovoltaic Cells and Dye-Sensitized Solar Cells Hébert M., Hammami A., Marsan B.
16:40 01138 Towards A New Liquid Crystal Material by a Combined Metalation-Cross Coupling Route Gan W., Snieckus V., Lemieux R.P.
16:40 01139 Diphenyl Borane-8-hydroxyquinolinate-Capped Linear and Starburst Complexes Cui Y., Wang S.
16:40 01140 Synthesis and Characterization of a New Class of Axial Chiral Dopants with a Chloro Substituted 2,2'-Spirobiindan-1,1'- dione Core Cui Q., Lemieux R.P.
16:40 01141 Novel Redox Couples for Electrochemical Solar Cell Application Correia Ledo D., Hammami A., Marsan B.
16:40 01142 New Indolocarbazole Derivatives for Application in Micro-Electronics Boudreault P.-L.
16:40 01143 Using Deuterium NMR Spectroscopy to Probe Chiral Perturbations in Ferroelectric Liquid Crystals Huntley C.M., Finden J.G., Yuh E., Lemieux R.P.

Wednesday AM

OR4CC-Mariner 5

Macromolecular and Supramolecular Chemistry (Joint with IN and MS) (joint with IN3)

Organizer(s) - Bruce Grindley
Chair(s) - Bruce Grindley

08:00 Joint with Inorganic Chemistry and Macromolecular Science and Engineering Divisions - See IN3

11:00 End of Session


REMINDER
11:00 Merck Frosst Centre for Therapeutic Research Award Lecture presented by Robert Batey in CC-Port Royal C1

OR7CC-Mariner 1

Organic Materials for Optical, Electronic or Photonic Applications (Joint with MS and MT) (joint with MS5)

Organizer(s) - Wayne Wang and Tim Bender
Chair(s) - Wayne Wang, William Skene

08:00 Joint with Macromolecular Science and Engineering and Materials Chemistry Divisions - See MS5

11:40 End of Session

OR8CC-Mariner 4

Organic Reaction Mechanisms

Organizer(s) - James Pincock and Frances Cozens
Chair(s) - Norman Schepp

08:40 01330 Mechanistic and Synthetic SET-Photochemistry Mariano‡ P.S.
09:20 01331 Photochromic Liposomes: Photoregulation of Membrane Permeability with Dithienylethenes Bai Y., Murphy R.S.
09:40 Coffee Break
10:00 01332 Design of Photoreleasable Protecting Groups which are Activated by Electron Transfer Reactions Falvey‡ D.E.
10:40 End of Session


REMINDER
11:00 Merck Frosst Centre for Therapeutic Research Award Lecture presented by Robert Batey in CC-Port Royal C1

OR10CC-Port Royal C1

Recent Advances in Organic Synthesis

Organizer(s) - Jean Burnell and Ian Pottie
Chair(s) - Graham Bodwell

08:00 01333 Synthesis of Single Isomer Tetrasubstituted Olefins Lemay A.B., Ogilvie W.W.
08:20 01334 Multicatalytic Processes: One-Pot Methylenation-Hydroboration-Cross-Coupling Reactions Ladjel C., Lebel H.
08:40 01335 Sythesis of Polypropionate Motifs Using Free-Radical Intermediates Guindon‡ Y.
09:20 01336 Cross-Coupling Reactions Using Acyclic Diamino Carbene (ADC) Ligands Thadani A.N., Dhudshia B.
09:40 Coffee Break
10:00 01337 Recent Advances in the Total Synthesis of Alkaloid Natural Products Martin‡ S.F.
10:40 01338 New Reactivity via Strained E-Cycloalkenes and E-Cycloalkenones Beauchemin A.M.
Merck Frosst Centre for Therapeutic Research Award Lecture presented by Robert Batey

Introduction of Robert Batey by Andrei Yudin

11:00 01339 Late-Transition Metal Catalyzed C-X Bond Formation: Synthetic Explorations and Applications Batey‡ R.A.
11:40 End of Session

OR11CC-Highland 10

General

Organizer(s) - Bruce Grindley
Chair(s) - David MaGee

08:00 01340 Preparation of Deuterated Oligo(ethylene glycol)-Linked Glycerols for Investigations of Cellular Membranes Schwan A.L., Faragher R.J.
08:20 01341 Highly Stereoselective Oxidative Esterification of Aldehydes with b-Dicarbonyl Compounds Yoo W., Li C.-J.
08:40 01342 Chiral Bisphosphine Monoxide as a New Class of Ligands in Catalytic Enantioselective Addition of Diorganozincs to b-Nitroalkenes Charette A.B., Côté A., Lindsay V.N.G.
09:00 01343 Synthesis of Aryl and Alkenylsulfones from Organoboronic Acids and Sulfinic Acid Salts Induced by a Catalytic Amount of Copper Huang F., Batey R.A.
09:20 01344 Conversion of Unsymmetrical Di- and Trisulfides to Tetra- and Hexasulfides Rys A.Z., Abu-Yousef I.A., Harpp D.N.
09:40 Coffee Break
10:00 01345 Accessing Functionalized Cyclophanes via En-yne Metathesis El-Azizi Y., Collins S.K.
10:20 01346 Using (TD) DFT to Calculate Ionization Potentials and Absorption Spectra of Cyclophanes as Model Systems for Base Pairs Kamya P.R.N., Muchall H.M.
10:40 01347 Reverse-Docking: A Computational Approach to the Study of Asymmetric Organocatalysts Deslongchamps G., Harriman D.J., Lambropoulos A., Landau J., Alemayehu M.
11:00 End of Session


REMINDER
11:00 Merck Frosst Centre for Therapeutic Research Award Lecture presented by Robert Batey in CC-Port Royal C1


Wednesday PM

OR1CC-CornwallisSuite

Carbohydrates and Drug Discovery (Joint with BM) (joint with BM2)

Organizer(s) - Bruce Grindley
Chair(s) - Robert Ben


REMINDER
13:00 Boehringer Ingelheim Award Lecture presented by Jason Kennedy in CC-Highland 7

13:40 Joint with Biological and Medicinal Chemistry Division - See BM2

17:00 End of Session

OR4CC-Port Royal C1

Macromolecular and Supramolecular Chemistry (Joint with IN and MS) (joint with IN3)

Organizer(s) - Bruce Grindley
Chair(s) - Bruce Grindley


REMINDER
13:00 Boehringer Ingelheim Award Lecture presented by Jason Kennedy in CC-Highland 7

13:40 Joint with Inorganic Chemistry and Macromolecular Science and Engineering Divisions - See IN3

17:00 End of Session

OR5CC-Mariner 4

Natural Products (Joint with BM) (joint with BM7)

Organizer(s) - Paul Harrison
Chair(s) - John Vederas


REMINDER
13:00 Boehringer Ingelheim Award Lecture presented by Jason Kennedy in CC-Highland 7

SYNTHESIS AND METABOLISM

13:40 Joint with Biological and Medicinal Chemistry Division - See BM7

17:00 End of Session

OR7CC-Mariner 1

Organic Materials for Optical, Electronic or Photonic Applications (Joint with MS and MT) (joint with MS5)

Organizer(s) - Wayne Wang and Tim Bender
Chair(s) - Michael Wolf, Stephan Eichhorn

13:00 Joint with Macromolecular Science and Engineering and Materials Chemistry Divisions - See MS5

16:40 End of Session

OR10CC-Highland 7

Recent Advances in Organic Synthesis

Organizer(s) - Jean Burnell and Ian Pottie
Chair(s) - Jean Burnell

Boehringer Ingelheim Award Lecture presented by Jason Kennedy

Introduction of Jason Kennedy by Graham Bodwell

13:00 01462 Stereogenic Quaternary Carbon Centres via Lewis Acid Catalysed Allylboration Kennedy‡ J.W.J., Hall D.G.
13:40 01463 Ruthenium-Mediated Cross Metathesis Reactions of Terminal Alkenes with Two Oxygen Functions Stamp C.T.M., Burnell D.J.
14:00 01464 The Synthesis of Cyclophanes Containing Nonplanar Polycyclic Aromatic Hydrocarbons Merner B.L., Bodwell G.J.
14:20 01465 Novel Electroactivated System for the Temporary Immobilisation and Protection of Amines on Electrode Surfaces and its Use as an Innovative Solid Support for Synthesis Giasson R., Pan Q.M.
14:40 Discussion

15:00 Coffee Break
15:20 01466 Reactive Intermediates in Organic Synthesis: Utilizing the Rearrangement of Allene Oxides to Produce Substituted Cyclopentenone Rings Konecny M., Schepp N.P.
15:40 01467 Stereoselective 6p Electrocyclization Reactions of Bridged Bicyclic Trienes Benson C.L., West F.G.
16:00 01468 New Methods For the Preparation of a-Chiral Allylic Boronate Reagents Using Metal-Catalyzed Substitution Reactions and Their Applications in the Synthesis of Oxygenated Heterocycles Peng F., Hall* D.G.
16:20 01469 Domino Reactions of Meldrum's Acid Alkylidenes Involving Friedel-Crafts Chemistry Fillion E., Dumas A.M., Hogg S.A, Kuropatwa A., Malhotra N.R., Sitler T.C.
16:40 End of Session


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