89th Canadian Chemistry Conference Abstracts


Inorganic Chemistry Division

Sunday AM

IN4CC-Mariner 2

Paramagnetic and Mixed-Valent Complexes in Organometallic and Inorganic Chemistry

Organizer(s) - Kevin Smith, Daniel Leznoff and Manuel Aquino
Chair(s) - Daniel Leznoff

08:00 00058 Coordination Chemistry with S,S-dithiolato(1-) Radicals and Ligand Mixed Valency Wieghardt‡ K.
08:40 00059 Metal Complexes of Sulfur-Nitrogen Spin-Bearing Ligands Preuss K.E., Hearns N.G. R., Wu J., Madhu N.T., Hesp K.
09:00 00060 Synthesis, Structures, and Magnetism of Transition Metal Complexes of Stable Verdazyl Radicals: The Ligand can be Paramagnetic too! Gilroy J.B., Lemaire M.T., McKinnon S.D.J., Koivisto B.D., Anderson K., Hicks R.G.
09:20 00061 Novel Products from Reactions between Paramagnetic Organometallics and Main Group Radicals Boeré R.T., Yu. X., Goh L.-Y., Ng V.W.L., Ang C.W.P., Kuan S.L., Lau H.F.
09:40 Coffee Break
10:00 00062 Self-Assembled Flat Poly-Metallic [nxn] Grids (n = 2,3,4,5) - Magnetic and Redox Active Platforms for Molecular Device Behaviour Dey S.K., Abedin T.S.M., Dawe L.N., Milway V.A., Thompson‡ L.K.
10:20 00063 Paramagnetic Metal-Cyanide Complexes with Tris(pyrazolyl)borate Ligands: Precursors for the Construction of High Nuclearity Metal-Cyanide Clusters DeGroot M. W., Harris T.D., Long J.R.
10:40 00064 Paramagnetic Organometallic Palladium Compounds: A Family That is No Longer Rare Harvey‡ P.D., Mugnier Y., Dalmolin S.
11:00 00065 Metal Complexes Incorporating Single or Double Deprotonated Benzimidazole-2-Carboxylic Acid: Structure and Magnetism Patrick B.O., Stevens C.L., Storr A., Storr T.J., Thompson R.C.
11:20 End of Session


REMINDER
11:25 Montreal Medal Lecture presented by Richard Puddephatt in CC-Port Royal C1

IN5CC-Port Royal C2

Recent Advances in Main Group Chemistry

Organizer(s) - Glen Briand
Chair(s) - Lisa Rosenberg

08:00 00066 New Aspects of the Chemistry of Dichalcogeno PNP Ligands Copsey M., Eisler D.J., Konu J., Ritch J.S., Chivers‡ T.
08:20 00067 Trimethylsilyl Aryl Selenides as Efficient Reagents in the Synthesis of Selenoesters Taher D., Corrigan J.F.
08:40 00068 P Ligands with CB2N2 and B2N3 Frameworks. Carbon-Free Cyclopentadienyl Analogs Ly H.V., Forster T.D., Parvez M., MacDonald R., Roesler‡ R.
09:00 00069 Unsual Phosphorus Species in Polymer Science and Catalysis Gates‡ D.P.
09:20 00070 Carboxylic Acids as Lewis Bases: Structures and Properties of Carboxylic Acid Adducts of B(C6F5)3 Mitu S., Baird M.C.
09:40 Coffee Break
10:00 00071 B/Hg Polydentate Lewis Acids: Anion Complexation and Electrochemistry Gabbai‡ F., Melaimi M.
10:40 00072 Facile and Atom Efficient Catalytic C-C and C-N Formation Using Bifunctional Main Group Catalysts Ong T.-G., Richeson D.S.
11:00 00073 Bifunctional Lewis Acid-Base Compounds Stephan‡ D.W., Welch G.C.
11:20 End of Session


REMINDER
11:25 Montreal Medal Lecture presented by Richard Puddephatt in CC-Port Royal C1


Sunday PM

IN4CC-Mariner 2

Paramagnetic and Mixed-Valent Complexes in Organometallic and Inorganic Chemistry

Organizer(s) - Kevin Smith, Daniel Leznoff and Manuel Aquino
Chair(s) - Manuel Aquino

13:40 00233 Toward NMR Spectroscopy of Paramagnetic Inorganic Solids Kroeker S., Aguiar P.M., Leznoff D.B.
14:00 00234 High-Field and Frequency Electron Paramagnetic Resonance (HFEPR) Studies of Cobalt(II) and Nickel(II) Scorpionate Complexes Telser‡ J., Krzystek J., Ozarowski A., Smirnov D., Desrochers P.J., Trofimenko S., Swenson D.C.
14:20 00235 EPR and Magnetic Susceptibility Studies of Malaria Pigment Analogues Kosar A.J., Bohle D.S., Suarez L.Y., Sienkiewicz A., Yee G.T.
14:40 00236 Theoretical Investigations of Paramagnetic Group 13-Diazabutadiene Complexes: Insights into the Interpretation and Simulation of EPR Spectra Tuononen H.M., Armstrong A.F.
15:00 Coffee Break
15:20 00237 Radical and/or Mixed-Valent Diruthenium Complexes - Criteria to Establish the True Nature of Paramagnetic Species Kaim‡ W.
16:00 00238 Mixed-Valence Ruthenium Complexes of the 4,4-Azo-di(phenylcyanamido) Dianion Bridging Ligand Crutchley‡ R.J., Al-Noaimi M.
16:20 00239 Modulation of Mixed Valency and Redox Potentials of CuA Center and its Roles in Controlling Proton-Coupled Electron Transfer in Biology Lu‡ Y., Hwang H.-J., Berry S.M.
16:40 End of Session

IN5CC-Port Royal C2

Recent Advances in Main Group Chemistry

Organizer(s) - Glen Briand
Chair(s) - Paul Ragogna

13:40 00240 Boron-Nitrogen Analogues of Polycyclic Aromatic Hydrocarbons: Synthesis, Structure and Properties Jaska C.A., Bosdet M., Emslie D.J.H., Piers* W.E.
14:00 00241 Synthesis and Unexpected Reactivity of Si-H Functionalized Dithieno[3,2-b:2',3'-d]phospholes Baumgartner T., Wilk W.
14:20 00242 Borane-Catalyzed S-Si Bond Formation Harrison D.J., Kobus D.N., Rosenberg L.
14:40 00243 Mechanistic Studies of Acid Catalyzed Dehydrocoupling of Ammonia-Borane Baker‡ R.T., Stephens F.H.
15:00 Coffee Break
15:20 00244 Verdazyl Radicals and Diradicals: Recent Advances in Synthesis and Electronic Structure Studies Gilroy J.B., McKinnon S.D.J., Koivisto B.D., Hicks‡ R.G.
15:40 00245 (CNSSS)2(A)2 (A = AsF6-, SbF6-, Sb2F11-): A Non-Sterically Hindered Main Group Diradical that Retains its Paramagnetism in the Solid State Cameron T.S., Decken A., Knapp C., Palacio F., Passmore J., Mawhinney R.C., Rautiainen J.M., Shuvaev K.V., Thompson R.C., Wood D.J.
16:00 00246 Radical Stereospecificity: Mechanistic Studies of Nitric Oxide's Addition to Nucleophiles Smith K.N., Bohle D.S.
16:20 00247 The Effect of Selenium Incorporation on the Bandwidth and Conductivity of Neutral Radical Conductors Brusso J.L., Oakley R.T., Reed R.W., Robertson C.M.
16:40 00248 Binary Sulfur-Nitrogen Radicals Boeré‡ R.T., Roemmele T.L., Chivers T., Tuononen H.M
17:00 End of Session

INPCC-Port Royal D,E

Posters

Organizer(s) - Neil Burford
Chair(s) - Neil Burford

From 17:00 until 19:00

See posters in other divisions with which there are joint symposia

17:00 00249 Studies of the Mechanism of Chromium Catalyzed Oligomerization of Ethylene Jabri A., Gambarotta S.
17:00 00250 Organized Molecular Architecture via Self-Assembly Dey S.K., Parson S.R., Thompson L.
17:00 00251 The Disassembly of Mixed-Valent Diruthenium(II,III) Tetracarboxylates as a Route to the Preparation of Novel Ru(II) Complexes Aquino M.A.S., Conrad E.D., Wallbank A.I., Murray A.H., MacLean B.J., Yue Z., Cameron T.S., Robertson K.N.
17:00 00252 Bis(phenoxide) Amine Complexes of Iron Roychowdhury R., Sheridan K., Kozak C.M.
17:00 00253 The Brook-Rearrangement of Diamidosilylether Ligands to Mixed-Donor Siloxo-Amino-Amido Ligands and their Coordination Chemistry Leznoff D.B., Haftbaradaran F., Kuchison A.M., Mund G., Katz M.J., Batchelor R.J., Schatte G., Britten J.F.
17:00 00254 Structure-Activity Relationships in the Activation of Iodomethane by Cyclopentadienyl Chromium(II) Complexes Smith K.M., Corcoran L.D., Tang L., Dickieson L.S.
17:00 00255 Synthesis and Characterization of [1]Metalloarenophanes Equipped with Heavier Group 13 Elements Lund C.L., Quail J.W., Müller J.
17:00 00256 Synthesis and Characterization of Fluorinated Phosphonium Ionic Liquids Tindale J.J., Ragogna P.J.
17:00 00257 Hemilabile Tridentate Iminophosphine Ligands: Applications to Ruthenium-Vinylidene and -Carbyne Chemistry Spivak G.J., Beach N.J., Walker J.M., Jenkins H.A.
17:00 00258 Formation of Metal Telluride Thin Films and Nanoplates from Novel Single-Source Precursors Ritch J.S., Eisler D.J., Chivers T., Sarje S.S., Afzaal M., O'Brien P.
17:00 00259 Interactions of Toxic Heavy Metals with Biologically Relevant Chelating Ligands Saunders C.D.L., Burford N.
17:00 00260 Kinetics of Catechol Oxidation by a Cobalt Salen in Organic Media: A Study on Peroxidase Mimicking Behavior Mahmoudi A., Khalafbeigi M., Nazari K., Dehghanpour S.
17:00 00261 Low Oxidation State Group 15 Compounds: Approaches to New P-Containing Polymers Norton E., Ellis B.D., Macdonald C.L. B.
17:00 00262 Low Oxidation State Group 13 Salts: Synthesis and Reactivities Cooper B.F.T., Macdonald C.L.B., Andrews C.G.
17:00 00263 Towards Neutral Phosphorus Analogs of N-Heterocyclic Carbenes Corrente A.M., Roesler R.
17:00 00264 A Mechanistic Approach to Ligand Exchange in Amidinates Using Density Functional Theory Brazeau A.L., DiLabio G.A., Barry S.T.
17:00 00265 Investigating Low Oxidation State Pnictogens: PI and AsI Salts Ellis B.D., Macdonald C.L.B.
17:00 00266 Further Developments in Fundamental catena-Cyclopolyphosphorus Cation Chemistry Riegel S.D., Burford N., Decken A.
17:00 00267 Synthesis and Coordination Chemistry of the 1,3,4-Triaza-3,5-diborolyl Ligand, a Carbon-Free Inorganic Analog of Cyclopentadienyl Ly H.V., Parvez M., McDonald R., Roesler R.
17:00 00268 Coordination Complexes of Alkali Metal-Crown Ether Cations with Group 13 Hydride Anions Onut L., McGrady G.S., Decken A.
17:00 00269 Novel Reactivity of 1,2-Di-tert-butylmethylenephosphine Bates J.I., Gates D.P.
17:00 00270 Substituent Effects on the Oligomerization of NP Analogues of Olefins Ovans R., Burford N.
17:00 00271 New Amidate Complexes of the Group 4 Metals: Stabilization of Highly Reactive Bond Fragments and their Stoichiometric and Catalytic Reactivity Thomson R.K., Schafer L.L.
17:00 00272 Synthesis and Spectroscopic Characterization of Novel Pt(II) Complexes Containing Sulfoxide Ligands and Pyrazine Priqueler J.R.L., Butler I.S., Rochon F.D.
17:00 00273 Novel Mixed-Ligands Pt(II) Complexes Containing a Pyridine Derivative and Pyrazine or Pyrimidine: Synthesis and Characterisation by IR and Multinuclear Magnetic Resonance Spectroscopies Rochon F.D., Fakhfakh M.
17:00 00274 DFT Study of S7, Se7 and Te7 Ring Systems Bajorek T., Laitinen R.S., Suontamo R.J.
17:00 00275 Coordinating Allenylidene Complexes as Models for Molecular Wire Systems Koutsantonis G.A., Lengkeek N.A., Sanford V., Schauer P.A., Skelton B. W., White A.H.
17:00 00276 Group IV Complexes of Hemilabile Ligand Systems Dureen M.A., Stephan D.W.
17:00 00277 Mechanistic studies of Methane Elimination from Organoscandium Dialkyl Complexes with bis-Pentafluorophenylborane Conroy K.D., Piers W.E., Parvez M.
17:00 00278 Thermal Decomposition of Ruthenium Phosphonium Alkylidenes van der Eide E.F., Piers W.E., Romero P.E., Dubberley S.R., McDonald R.
17:00 00279 Reactions of Secondary Phosphines with Transition Metals: Co-Ordination and P-H Bond Activation Geier S.J., Masuda J.D., Stephan D.W.
17:00 00280 Synthesis and Reactivity of Group 8 Silylene and Silylyne Complexes Hayes P.G., Waterman R., Tilley T.D.
17:00 00281 High-Pressure Micro-Raman Spectroscopic Investigation of Ternary Metal Hydrides and their Deuteride Analogues Barsan M.M., Moyer Jr. R.O., Butler I.S., Gilson D.F.R.
17:00 00282 Structure of Bismuth(III) Complexes with Cysteine in Aqueous Solution and the Solid State Schell A.C., Jalilehvand F.
17:00 00283 Synthesis of Novel Selenosulfide Reagents used in the Formation of Molecular Complexes and Nanoclusters Containing Both Sulfur and Selenium Turner E.A., Huang Y., Corrigan J.F.
17:00 00284 Positional Grafting Palladium onto SBA-15 Allen D.P., Webb J.D., Crudden C.M.
17:00 00285 A Metal-Organic Framework with a Hierarchical System of Pores and Supertetrahedral Building Blocks Cote A.P., Sudik A.C., Wong-Foy A.T.K., O'Keeffe M., Yaghi O.M.
17:00 00286 Developing a New Ionic Hydrogenation Catalyst for the Selective Deoxygenation of Glycerol Dykeman R., Schlaf M.
17:00 00287 Synthesis and Characterization of Novel Benzimidazole Functionalized Ligands White W. M., Wang S.
17:00 00288 Intra- and Intermolecular Interactions in Square-Planar d8 Complexes Probed by Pressure-Dependent Luminescence Spectroscopy Reber C.
17:00 00289 Synthesis and Catalytic Activity of Titanium Oxazoline Complexes Etkin N., MacDonald J.K., Gossage R.A.
17:00 00290 Synthesis, Characterization and Redox Properties of New Phosphine Quinones Caldwell S.L., Hicks R.G.
17:00 00291 Synthesis and Characterization of Verdazyl Ligands and Metal-Verdazyl Ccomplexes Anderson K.J., Hicks R.G.
17:00 00292 Group VI Metal Imido Complexes bearing N,N'-Disubstituted 1,8-Diaminonaphthalene Ligands Lavoie N., Ong T.G., Richeson D.S.
17:00 00293 Electrospray Ionization Mass Spectra from Non-Polar Solvents McIndoe J.S., Henderson M.
17:00 00294 A 12-Hydride-Rhodium Cluster that Reversibly Adds Two Molecules of H2 McIndoe J.S., Weller A.S.
17:00 00295 Formation of a Dinuclear Ni(I) Complex via C-H Bond Activation Keen A.L., Johnson S.A.
17:00 00296 Synthesis, Reactivity and Catalytic Applications of Group IV and V Transition Metal Complexes Supported by Diaminonapthalene-Based Ligands O'Brien J.S., Ong T.G., Richeson D.S.
17:00 00297 Coordination Polymers based on Ag(I): Mixed-Donor Systems to Promote Closed-Shell Interactions Jenkins H.A., Beaton S.A., Jacobs J.-L., Merchant S.
17:00 00298 The Development of Ruthenium-Based Bifunctional Catalysts for the Selective Deoxygenation of Glycerol Thibault M.E., Schlaf M.
17:00 00299 Stereochemistry of the Products of Nucleophilic Addition to Pt Coordinated Alkene Complexes Bickley D.G., Jessop P.G.
17:00 00300 Pressure-Dependent Luminescence Spectroscopy of Molybdenum(IV) Oxo Complexes Reber C., Lanthier E.
17:00 00301 Use of Platinum and Nickel Phosphine Macrocyclic Clusters as Templating Reagents in C-C Coupling Reactions Scoles L., Martin-Redondo M.P., Sterenberg B.T., Udachin K.A., Carty A.J.
17:00 00302 Metal Complexes with Potential Tetradentate Bridging Chelators Gruia L., Rochon F., Beauchamp A.L.
17:00 00303 Using ESI-MS/MS Fragmentation Analysis to Screen the Coordination Geometry of Diamagnetic Surrogate Metals Expected to Mimic Cu2+-binding to the Mammalian Prion Protein Octarepeat Region Pushie M.J., Vogel H.J.

Monday AM

IN1CC-CornwallisDraped

Inorganic Solid State Chemistry (Joint with MT) (joint with MT4)

Organizer(s) - Mario Bieringer and Arthur Mar
Chair(s) - Arthur Mar

08:00 00447 Synthesis, Magnetic Properties and Structures of the Pillared Perovskites, La5Re2TaMO16 (M = Mn, Fe, Co, Ni) Cuthbert H.L., Greedan J.E.
08:20 00448 Polar Nanostructure and Dynamics of Relaxor Ferroelectrics Ye‡ Z.-G.
09:00 00449 Anatomy of the Mott Transition in Vacancy-Doped Nd1-xTiO3 Greedan‡ J.E., Safa-Sefat A.
09:20 00450 Inorganic-Organic "Hybrid" High-Temperature Magnets Jain R., Hicks R.G.
09:40 Coffee Break

REMINDER
10:00 Pure or Applied Inorganic Chemistry Award Lecture presented by Heinz-Bernhard Kraatz in CC-Mariner 5

10:40 00451 Crystal Structure Evolution and Magnetism in Sc(1-x)LuxVO3 (0®x®1) Bieringer M.
11:00 00452 Structural Properties of Framework Materials Evans‡ J.S.O., Stinton G.W., Lister S.E.
11:40 End of Session

IN3CC-Mariner 5

Macromolecular and Supramolecular Chemistry (Joint with MS and OR) (joint with OR4)

Organizer(s) - Bruce Grindley
Chair(s) - Laurence Thompson

08:20 00453 Novel Star-Shaped Organoiron Molecules and their Polymerizations Abd-El-Aziz A.S., Shipman P.O., Carruthers S.A., Pereira N.M.
08:40 00454 [2×2] and [3×3] Grid, and Pentanuclear Cluster Complexes: Structural, Magnetic and Electrochemical Studies Dawe L.N., Thompson L.K.
09:00 00455 Functionalized Mn(II)9 [3x3] Grids: Intermolecular Interactions and Secondary Coordination Milway V.A., Thompson L.K., Dawe L.N., Miller D.O.
09:20 00456 Building Block Approach to the Assembly of Zeolite-Like Metal-Organic Frameworks (ZMOFs) Eddaoudi M., Liu Y., Larsen R.
09:40 Coffee Break
Pure or Applied Inorganic Chemistry Award Lecture presented by Heinz-Bernhard Kraatz

Introduction of Heinz-Bernhard Kraatz by Ron Steer

10:00 00457 Redox Active Peptides: From Macrocycles to Barrels and Helicates Kraatz‡ H.B.
10:40 00458 Luminescent and Microporous Metal-Organic Frameworks Formed by a Stepwise Assembly Approach Shimizu G.K., Chandler B.D., Cramb D.T.
11:00 End of Session


REMINDER
11:00 Alfred Bader Award Lecture presented by Mark Lautens in CC-Port Royal C1

IN4CC-Mariner 2

Paramagnetic and Mixed-Valent Complexes in Organometallic and Inorganic Chemistry

Organizer(s) - Kevin Smith, Daniel Leznoff and Manuel Aquino
Chair(s) - Kevin Smith

08:00 00459 New Sterically Protected Paramagnetic Organometallic Hydrides Poli‡ R., Baya M., Houghton J., Daran J.-C., Male L., Albinati A.
08:40 00460 Correlation Between Metal Spin State and Catalytic Reactivity: Polymerizations Mediated by a-Diimine Iron Complexes Shaver M.P., Allan L.E. N, Rzepa H.S., Gibson V.C.
09:00 00461 Spin State, Unsaturation, and Pi-Donation: Impact on Reactivity? Caulton‡ K.G.
09:20 00462 Paramagnetic or Not - And Does it Matter? Budzelaar‡ P.H.M.
09:40 Coffee Break

REMINDER
10:00 Pure or Applied Inorganic Chemistry Award Lecture presented by Heinz-Bernhard Kraatz in CC-Mariner 5

10:40 00463 Oxidatively-Induced a-H Abstraction: A Convenient Protocol to Reactive Ti=C and Ti«C Linkages Bailey B.C., Basuli F., Huffman J.C., Baik M.-H., Mindiola‡ D.J.
11:00 00464 Synthetic Routes to (LLL)FeR2 Complexes Phillips C.D., Kleckner J.R., McNeil W.S.
11:20 00465 Small Molecule Activation with Chromium(I) Complexes Theopold‡ K.H., Kreisel K.A., Monillas W.H., Yap G.P.A.
11:40 End of Session

IN5CC-Port Royal C2

Recent Advances in Main Group Chemistry

Organizer(s) - Glen Briand
Chair(s) - Charles Macdonald

08:00 00466 SBIs: Chemical Bonds that were not Supposed to Exist Vargas-Baca‡ I., Cozzolino A.F., Elder P.J.W.
08:20 00467 Recent Advances in the Synthesis and Characterization of New Cyclic catena-Polyphosphorus Dications Weigand J.J., Burford N., Decken A., Lumsden M.
08:40 00468 Homogeneous, Early Transition Metal-Catalyzed Dehydrocoupling of Group 13/15 Adducts Clark T.J., Manners I.
09:00 00469 Homoleptic Thiolates of Groups 12, 14 and 16 as Precursors for Binary Composite Semiconducting Materials Fleischer‡ H.
09:40 Coffee Break

REMINDER
10:00 Pure or Applied Inorganic Chemistry Award Lecture presented by Heinz-Bernhard Kraatz in CC-Mariner 5

10:40 00470 Mechanisms for Synthesis and Thermolysis of Main Group Amidinates and Guanidinates Barry‡ S.T.
11:00 00471 Synthesis, Molecular and Electronic Structures of the Cyclic [N(PR2E)2]+ (E = Se, Te; R = iPr, Ph) Cations Konu J., Chivers T., Tuononen H.M.
11:20 00472 Synthetic Routes to Heteroleptic Indium(III) Thiolates Briand‡ G.G., Cooper B.F.T., MacDonald D.B.S., Martin C.D., Schatte G.
11:40 End of Session


Monday PM

IN1CC-Mariner 2

Inorganic Solid State Chemistry (Joint with MT) (joint with MT4)

Organizer(s) - Mario Bieringer and Arthur Mar
Chair(s) - Zuo-Guang Ye


REMINDER
13:00 Alcan Award Lecture presented by Neil Burford in CC-Port Royal C2

13:40 00569 Crystal Structure, Vibrational Spectra and Thermal Decomposition of a New Tetramanganese(II) Dipyrophosphate Decahydrate, Mn4(P2O7)2.10H2O Assaaoudi H., Butler I.S., Kozinski J.A.
14:00 00570 Hydrothermal Synthesis of Oxides and Phosphates Whittingham‡ M.S.
14:40 00571 Gas Capture and Release by Conversion Between Open and Closed Pore Structures in a Crystalline Metal Organic Framework Shimizu G.K., Chandler B.D., Enright G.D., Cramb D.T.
15:00 Coffee Break
15:20 00572 Thermoelectric Properties of Transition Metal Tellurides Assoud A., Soheilnia N., Kleinke‡ H.
16:00 00573 Structures and Properties of Highly Anisotropic Ternary Uranium Transition-Metal Antimonides Tougait O., Noël H., Mar A.
16:20 00574 Chemistry of the Giant Magnetocaloric Effect Material Gd5Si2Ge2 and Related Phases Mozharivskyj‡ Y.
17:00 End of Session

IN5CC-Port Royal C2

Recent Advances in Main Group Chemistry

Organizer(s) - Glen Briand
Chair(s) - Sean Barry

Alcan Award Lecture presented by Neil Burford

Introduction of Neil Burford by Tris Chivers

13:00 00575 Homoatomic P-P Coordination Complexes: A New Direction in the Chemistry of Phosphorus Burford‡ N.
13:40 00576 N-Silylphosphoranimine Cations Bearing P-P Coordination Bonds: Synthesis, Structure, and Reactivity Huynh K., Lough A.J., Manners I.
14:00 00577 New N-Heterocyclic Pnictogenium Cations Containing a Diamidonaphthalene Framework Spinney H.A., Richeson D.S.
14:20 00578 Ultra High Bandwidth Thiazyl Radical Conductors Leitch A.A., Oakley R.T., Reed R. W., Thompson L.K.
14:40 00579 Synthesis of Se-N Rings via 1,4-Di(tert-butyl)-2,3-diazabutadiene and the Development of Ferrocene Substituted Phosphonium Ionic Liquids Ragogna‡ P.J., Dutton J.L., Breadner D.
15:00 Coffee Break
15:20 00580 New Developments in Low Oxidation State Main Group Chemistry Macdonald‡ C.L.B., Ellis B.D., Norton E.L., Morasset E.V, Corrente A.M., Gueorguieva D.E.
15:40 00581 Sandwich Compounds with Bridging Heavier Group 13 Elements. Trisyl-Based Donor Ligands for Stabilizing Strained Organometallic Species Lund C.L., Schachner J.A., Quail J.W., Müller J.
16:00 00582 m-Terphenyl Carboxylates in Low Coordinate Main Group Complexes Dickie D.A., Clyburne‡ J.A.C.
16:20 00583 Unusual Electrochemistry of [1.1]Ferrocenophanes Containing Heavier Group 13 Elements (M = Al, Ga, In) Schachner J.A., Orlowski G.A., Lund C.L., Quail J.W., Kraatz H.B., Müller J.
16:40 00584 Cyclic Dimethylsiloxanes as Pseudo Crown Ethers: Syntheses and Characterization of Li(Me2SiO)5[Al(OC(CF3)3)4], Li(Me2SiO)6[Al(OC(CF3)3)4] and Li(Me2SiO)6[Al(OC(CF3)2Ph)4] Passmore‡ J., Wang X., Decken A.
17:00 End of Session

IN6CC-CornwallisDraped

Semiconductor and Metal Nanoparticles: Synthesis, Properties and Applications (Joint with MT) (joint with MT8)

Organizer(s) - Matthew Moffitt and Michael Wolf
Chair(s) - Michael Wolf


REMINDER
13:00 Alcan Award Lecture presented by Neil Burford in CC-Port Royal C2

13:40 00585 Synthesis and Surface Functionalization of Metal-Oxide and Semiconductor Nanoparticles Veinot‡ J.G.C.
14:20 00586 Synthesis and Characterization of Colloidal CuInS2 Particles for Solar Cell Technology Courtel F., Imbeault R., Hammami A., Morin M., Paynter R.W., Marsan B.
14:40 00587 Functionalized Superparamagnetic Nanoparticles as Pathogen Capture Probes Kell A.J., Simard B., Stewart G., Peytavi R., Huletsky A., Boissinot M., Bergeron M.G.
15:00 Coffee Break
15:20 00588 Towards Device-Integrated Multi-Functional Magnetic Nanoparticles Cameron N.S., Ledrogoff B., Roberge H., Normandin F., Veres T.
15:40 00589 Watching Glass Grow with Nanoplasmonics Andrews M.P., Glasspoole B., Maron E.
16:00 00590 Thiolate-Capped PbS Nanocrystals in Water: Sensitivity to O2, pH and Concentration, an Alternate Pathway for Crystal Growth and a Top-Down Synthesis Cornacchio A.L.P., Jones N.D.
Keith Laidler Award Lecture presented by Gregory Scholes

Introduction of Gregory Scholes by David Cramb

16:20 00591 Photophysics of Nanoscale Materials: The Question of Shape Scholes‡ G.D.
17:00 End of Session

IN7DH-Baronet 6

General

Organizer(s) - Neil Burford
Chair(s) - Mark Stradiotto


REMINDER
13:00 Alcan Award Lecture presented by Neil Burford in CC-Port Royal C2

13:40 00592 Synthesis, Thermolysis, and Film Deposition of Hafnium and Zirconium Precursors Wasslen Y.A.M., Kenney A.P., Wang Z., Barry S.T.
14:00 00593 Group 4 Amidate Complexes with M=E Multiple Bonds: Applications in Catalytic Olefin Hydroamination and Small Molecule Activation Thomson R.K., Schafer L.L.
14:20 00594 Rh(I) and Ir(I) Derivatives of a P(S),N-Substituted Indene Ligand: Synthetic and Structural Studies and the Application in Catalytic Alkene Hydrosilylation Wechsler D., Myers A., Stradiotto M.
14:40 00595 Synthesis and Characterization of Chiral N,N-Chelating Oxazolidine Ligands and their Platinum and Palladium Complexes Cardile S.A., Jennings M.C., Jones N.D.
15:00 Coffee Break
15:20 00596 Thiol Modified Mesoporous Silica as a Ligand for a Leach Free Palladium Catalyst for Suzuki-Miyaura and Sonogashira Coupling McEleney K., Finnamore D., Mutyala S., MacQuarrie S.L., Blanc A.C., Crudden C.M.
15:40 00597 Analogues of Titanocene Dichloride as Potential Anti-Tumour Agents Potter G.D., Baird M.C., Chan M., Cole S.P.C
16:00 00598 Remarkably Stable Base-Free Thorium(IV) Dialkyl Complexes by Alkane Elimination: A Novel Route into Organoactinide Chemistry Cruz C.A., Emslie D.J.H.
16:20 00599 Diimine Ligands Continued: Synthesis and Characterization of c-Diimine Ligands and their use in the Formation of Late Transition Metal Complexes Foley S.R., Chitanda J.M., Quail J.W.
16:40 00600 Synthesis and Reactivities of some New Pincer Complexes of Nickel Castonguay A., Zargarian* D., Beauchamp* A.L.
17:00 End of Session

INPCC-Port Royal D,E

Posters

Organizer(s) - Neil Burford
Chair(s) - Neil Burford

From 17:00 until 19:00

See posters in other divisions with which there are joint symposia

17:00 00601 The Ternary Zr-Pt-Sb System Tkachuk A.V., Mar A.
17:00 00602 Study of Magnetism of Face-Center-Cubic Double Perovskite Compounds Aharen T., Greedan J.E.
17:00 00603 Ternary Rare-Earth Manganese Bismuthides, RE3MnBi5 (RE = La, Pr): Structure and Properties Zelinska O.Ya., Mar A.
17:00 00604 NMR Studies of Solids under Pressure and Uniaxial Stress Werner-Zwanziger U., Shaw J., Zwanziger J.W.
17:00 00605 New Phase Transitions in the LaTaOx Structure Witzke A., Bieringer M.
17:00 00606 Investigation of Novel Phases in the Indium Vanadium Oxide Phase Diagram Lundgren R., Bieringer M.
17:00 00607 Thermal Properties of ZrW2O8 and HfMo2O8 Stancescu M., Kennedy C.A., White M.A.
17:00 00608 Structure Property Correlations in the Stress-Optic Response of Glass Guignard M., Zwanziger J.W., Werner-Zwanziger U., Shaw J.L.
17:00 00609 Synthesis, Characterization and Reactivity of Mesoporous Palladium/Yttria-Stabilized-Zirconia for Gas and Solution Phase Reactions Poulin C., Brown M., Duschesne M., Wesslen Y., Grgicak C., Fagnou K., Giorgi J.
17:00 00610 Characterization of Amorphous Phases Formed during AlPO4-5 Synthesis Longstaffe J.G., Huang Y.
17:00 00611 Investigation of Rare-Earth Containing Oxychlorides Campbell J.K., Bieringer M.
17:00 00612 Synthesis and Application of Late Transition Metal Complexes with Iminophosphinite Ligands Beaton S., Yorke J., Xia A.
17:00 00613 New Metallation Resistant Bulky b-Diketiminato Ligands and their Scandium Complexes Ross J.A., Piers W.E., Parvez M.
17:00 00614 Ligand Design Towards Novel Early Transition Metal Olefin Polymerization Catalysts Yadav K., Stephan D.W.
17:00 00615 Development of New Methods for the Preparation of Aminocalixarenes Hobbs M.G., Roesler R.
17:00 00616 Chiral Oxazolinylamine-Based Ligands for Asymmetric Catalysis Caputo C.A., Carneiro F.D.S., Jennings M.C., Jones N.D.
17:00 00617 Reactivity Study of Late Transition Metal Complexes with Novel 7-Azaindolyl Derivative Ligands Zhao S.B., Wang S.
17:00 00618 Metallic Proton Sponges: Electrospray Active Bipyridyl Ligands Chisholm D., McIndoe J.S.
17:00 00619 Proton Sponge Phosphines: Electrospray-Active Ligands McIndoe J. S., Farrer N.J.
17:00 00620 Highly Active Mono(b-Enaminoketonato) Vanadium(III) Polymerization Catalysts Tang L., Li Y.
17:00 00621 Theoretical Charge Density Studies on Metal Silane Bonding Sirsch P., McGrady G.S.
17:00 00623 Synthesis, Characterization and Bioactivity of S-n-Picolyldithiocarbazate Ligands and some of their Metal Complexes Crouse K.A., M. Tahir M.I., Khoo T.-J.
17:00 00624 Size and Crystal Structure Control of Iron Oxide Nanoparticles Macdonald J.E., Boates K.M., Veinot J.G.C.
17:00 00625 Biosensors Using Quantum Dot/Aptamer-Based Complexes Revesz E., Lai E.P.C., DeRosa M.
17:00 00626 Direct Nitric Oxide Detection: Utilizing ZnO Nanocrystals towards the Development of a Spatial-Temporal Sensor for Nitric Oxide Spina C.J., Bohle D.S.
17:00 00627 Gold Nanoclusters Dispersed in a Nematic Liquid Crystal: Studying Optically Activity and Long-Range Ordering Qi H., Hegmann T.
17:00 00628 Ligand-Exchange Reactions of 4-(N,N-Dimethylamino)pyridine on Gold Nanoparticles Rucareanu S., Gandubert V., Lennox R.B.
17:00 00629 Oligo(ethylene glycol)-Stabilized Gold Nanoparticles for Nanofluid Applications Corbierre M.K., Nikanpour D.
17:00 00630 Synthesis and Characterization of Surface Functionalized Europium Sulfide Nanocrystals Mirkovic T., Nair S., Hines M., Scholes G.
17:00 00631 Switchable Self-Assembly of Magnetic Nano-Disks Cameron N.S., Geissler M., Roberge H., Veres T.
17:00 00632 Amphiphilic Gold and Palladium Nanoparticles Bari A., Tadayyon S., Norton P.R., Eichhorn S.H
17:00 00633 Stable Ag-Doped Siloxanes for Photolithography of Metallodielectric Structures Qiu L., Rewari A., Saravanamuttu K.
17:00 00634 Tailoring the Emission Properties of Nanocrystalline Silicon Hessel C., Henderson E.J., Wenger D.M., Veinot J.G.C.
17:00 00635 Synthesis and Characterization of Late Transition Metal Complexes Using a Phosphine-Thioxanthene-Borane Ligand Oakley S.R., Emslie D.J.H.

Tuesday AM

IN1CC-Mariner 2

Inorganic Solid State Chemistry (Joint with MT) (joint with MT4)

Organizer(s) - Mario Bieringer and Arthur Mar
Chair(s) - Mario Bieringer

08:00 00867 NMR Study of Silicon Oxyfluoride Glasses Karpukhina N.G., Zwanziger J.W., Werner-Zwanziger U., Kiprianov A.A.
08:20 00868 Probing the Self-Assembly Process of Microporous Materials by Solid-State NMR Spectroscopy Chen B., Yan Z., Kirby C.W., Huang‡ Y.
09:00 00869 b Detected NMR: A New Probe of the Electronic and Magnetic Properties of Thin Solid Films MacFarlane‡ W.A., Chow K.H., Song Q., Dong W., Hossain M.D., Keeler T., Kiefl R.F., Kreitzman S.R., Levy C.D.P., Morris G.D., Parolin T.J., Chu R., Saadaoui H.X., Salman Z., Valiani J.
09:40 Coffee Break
10:00 00870 Novel Intercalation Compounds of Molybdenum Diselenide Bissessur R., Xu H.
10:20 00871 Acidic Properties and Catalytic Activities of Mesoporous Niobium Oxides by the Benzylation of Anisole and Toluene with Benzyl Alcohol Rao Y., Antonelli D.M.
10:40 00872 Solution Phase Synthesis of Nanoparticles of Complex Metal Oxides Gates B.D., Wood B.D., Shafiee N.M.
11:00 00873 Synthesis and Characterization of ME and MM'E [M = Zn, Cd, Hg; E = S, Se, Te] Nanomaterials in MCM-41 and SBA-15 Using Silylated-Chalcogen Reagents Turner E.A., Huang Y., Corrigan J.F.
11:20 End of Session


REMINDER
11:25 CIC Medal Lecture presented by Ronald Kluger in CC-Port Royal C1

IN2CC-Port Royal C2

Ligand Design in Transition Metal Chemistry

Organizer(s) - Mark Stradiotto
Chair(s) - Samuel Johnson

08:00 00874 New Pyrrole-Based Ligands for Ethylene Trimerization Gambarotta‡ S.
08:20 00875 The Discovery and Development of New Stereospecific Polypropylene Polymerization Catalysts Using High-Throughput Techniques Diamond G.M., LaPointe A.M., Leclerc M.K., Longmire J.M., Murphy V., Shoemaker J.A.W., Turner H.
08:40 00876 New Generation b-Diketiminato Ligands for Group 3 Organometallic Compounds with a Reduced Proclivity to Metallate Piers‡ W.E., Ross J.A., Knight L.K., Kenward A.L., Parvez M., McDonald R.
09:00 00877 Complexes of Amine-Bis(phenolate)-Donor Ligands: From Structural Diversity to Reactivity Kozak C.M., Roychowdhury R., Kerton F.M.
09:20 00878 New Hemi-Labile Ligands in Early and Late Transition Metal Chemistry Stephan‡ D.W., Ghesner I., Das A., Geier S., Dureen M., Yadav K.
09:40 Coffee Break
10:20 00879 Gold and Silver Complexes as Homogeneous Catalysts for Transformations Involving E-H Bonds Wile B.M., Stradiotto M.
10:40 00880 Ruthenium Trihydrides with N-Heterocyclic Carbene Ligands: Effects on Quantum Mechanical Exchange Coupling Jones A.L., McGrady‡ G.S., Sirsch P., Steed J.W.
11:00 00881 Design and Synthesis of a Carbene Ligand and Applications in Transition Metal Chemistry Richeson‡ D.S., Bazinet P., Ong T.-G., Lavoie N., O'Brien J.S., Yap G.P.A., Perron E.
11:20 End of Session


REMINDER
11:25 CIC Medal Lecture presented by Ronald Kluger in CC-Port Royal C1

IN3CC-Mariner 5

Macromolecular and Supramolecular Chemistry (Joint with MS and OR) (joint with OR4)

Organizer(s) - Bruce Grindley
Chair(s) - Steve Loeb

08:40 00882 Interactions of Well-Defined, Pyrene-Functionalized Block Copolymers with Single-Walled Carbon Nanotubes Bahun G.J., Adronov A.
09:00 00883 Synthesis and Characterization of Periodic Mesoporous Organosilicas with Substituted Biphenyls MacQuarrie S.L., Crudden C.M., Montoya-Pelaez P.J., Blanc A.C., Uh Y.S., Lata C.
09:20 00884 Design and Synthesis of Photoactive Supramolecular Complexes Based on Coordination-Driven Self-Assembly Georgiev I.G., MacGillivray L.R
09:40 Coffee Break
10:00 00885 Metal-Organic Nanostructures as Building Blocks and Functional Materials McManus G.J., Zaworotko M.J.
10:20 00886 The Effect of Alkoxy and Aryloxy Pendant Groups on the Superstructural Diversity Found in Metal-Organic Frameworks Perry IV J.J., Zaworotko M.J.
10:40 00887 Design of Single-Crystal-to-Single-Crystal Reactivity of Multicomponent Supramolecular Assemblies via Crystal Size Control Bucar D.-K., MacGillivray L.R.
11:00 00888 Conversion of Helical Mononuclear Complexes to Tetranuclear Metallomacrocycles Hanan G.S., Medlycott E.A.
11:20 End of Session


REMINDER
11:25 CIC Medal Lecture presented by Ronald Kluger in CC-Port Royal C1

IN7CC-Highland 7

General

Organizer(s) - Neil Burford
Chair(s) - Glen Briand

08:00 00889 New Synthetically Useful Indium(I) Reagents: Syntheses and Reactivities Andrews C.G., Cooper B.F.T., Corrente A.M., Macdonald C.L.B.
08:20 00890 Silver-Cyclic Dimethylsiloxane Complexes: Ag+ Cation Catalyzed Ring Transformation Wang X., Decken A., LeBlanc F., Passmore* J.
08:40 00891 Living Anionic Polymerization of P=C Bonds Noonan K.J.T., Gates D.P.
09:00 00892 Synthesis, Thermolysis and Deposition of Volatile Group 13 Precursors Kenney A.P., Wang Z.H., Brazeau A.L., Barry* S.T.
09:20 00893 New Developments in Fundamental Phosphorus Chemistry: Linear catena-Polyphosphorus Cations Dyker C.A., Buford N., Decken A., Lumsden M.
09:40 Coffee Break
10:00 00894 Transition Metal Complexes of Cyclopentadienylidene Ylides Brownie J.H., Baird M.C.
10:20 00895 En route to the Construction of Non-Disjoint Thiazyl Based Biradicals Originating from Quinones Mailman A., Passmore J.
10:40 00896 Identification and Isolation of Intermediates in the Lewis Acid Induced Ring Expansion of Cyclodipnictazanes to the Corresponding Cyclotripnictazanes Burford N., Landry J.C.
11:00 00897 An Anionic Six-Membered N-Heterocyclic Carbene with an Inorganic Backbone Krahulic K.E., Forster T.D.K., Roesler R., Parvez M., McDonald R.
11:20 End of Session


REMINDER
11:25 CIC Medal Lecture presented by Ronald Kluger in CC-Port Royal C2


Tuesday PM

IN2CC-Port Royal C2

Ligand Design in Transition Metal Chemistry

Organizer(s) - Mark Stradiotto
Chair(s) - Laura Turculet

13:40 01037 Can Salim Functionalised Carbene Ligands Facilitate Communication Between Metal Centres? Kühl O., Aeduengo III A.J., Kim H.-Y.
14:00 01038 Rhodium(III) Peroxo Complexes with Carbene and Phosphine Ligands James B.R., Yu X.-Y, Patrick B.O.
14:20 01039 Reactions of Transition Metal Bisdithiolenes with Alkenes Fekl U., Harrison D., Nguyen N., Kogut E.
14:40 01040 Polynuclear and Heteronuclear Complexes Supported by a Tripodal-Amido Ligand with a Non-Chelating Phosphine Donor Johnson‡ S.A., Keen A.L., Raturi R., Han H., Hatnean J., Doster M.
15:00 Coffee Break
15:20 01041 Amidate Complexes of Early Transition Metals for Catalytic C-N Bond Formation Schafer‡ L.L.
15:40 01042 The Design and Synthesis of New Helical Metal Complexes for Asymmetric Catalysis Levy C.J., Wiznycia A.V.
16:00 01043 Transition Metal-Catalyzed Activation of Nitrogen Derivatives Lebel‡ H.
16:20 01044 Modular Syntheses of Chiral Nitrogen Donor Ligands Jones N.D., Caputo C.A., Cardile S.A., Carneiro F.D.S., Dodd D. W., Jennings M.C.
16:40 End of Session

IN6CC-Mariner 2

Semiconductor and Metal Nanoparticles: Synthesis, Properties and Applications (Joint with MT) (joint with MT8)

Organizer(s) - Matthew Moffitt and Michael Wolf
Chair(s) - Matthew Moffitt

13:40 01045 Making and Derivatizing Gold Nanoparticles Kassam A., Corbierre M., Rucareanu S., Gandubert V., Beerens J., Beauvais J., Lennox‡ R.B.
14:20 01046 Probing Gold Nanoparticle Chirality in Nematic Liquid Crystal Phases Qi H., Hegmann T.
14:40 01047 Metal Nanoparticles Assembled in 1- and 2-Dimensions in a Controlled Fashion Corbierre M.K., Beerens J., Beauvais J., Lennox R.B.
15:00 Coffee Break
15:20 01048 Systematically Controlling the Structure of Metal Nanoparticles Zhang P.
15:40 01049 Electrochemical Properties of Ferrocenylalkane Dithiol-Gold Nanoparticle Films Prepared by Layer-by-Layer Self-Assembly Escorcia A., Dhirani A.-A.
16:00 01050 Electronic and Optical Properties of Electrodeposited Oligothiophene-Linked Gold Nanoparticle Films Sih B.C., Wolf M.O.
16:20 01051 Chemistry and Electrochemistry of 1-2 nm Au Nanoparticles Murray‡ R. W.
17:00 End of Session


Wednesday AM

IN2CC-Port Royal C2

Ligand Design in Transition Metal Chemistry

Organizer(s) - Mark Stradiotto
Chair(s) - Laurel Schafer

08:00 01284 Ni(II) and Ni(III) Complexes of Pincer-Type POCsp3OP and POCsp2OP Ligands Zargarian D., Pandarus V.
08:20 01285 New Ligand Designs for the Activation of Molecular Nitrogen by Early Transition Metal Complexes Fryzuk‡ M.D., MacLachlan E.A., Morello L., MacKay B.A., Spencer L.P.
08:40 01286 A Phosphine/Thioether/Borane Ligand for the Preparation of Borane-Appended Late Transition Metal Complexes Emslie D.J.H., Huk N.L., Oakley S.R., Parker K.D.J., Blackwell J.M.
09:00 01287 The Chemistry of Ruthenium, Osmium, and Rhenium Complexes with New Pincer Ligands Gusev‡ D., Major Q.
09:20 01288 Reactivity and Catalysis Based on Adaptable Pincer-Ligand Systems Milstein‡ D.
09:40 Coffee Break
10:00 01289 Ligand Strengths and Vulnerabilities: Some Case Studies Caulton‡ K.G.
10:20 01290 New Bond Activations at Transition Metal Centers. Fundamental Studies and Applications to Catalysis Tilley‡ T.D., Hayes P.G., Karshtedt D., Escalada J.
10:40 01291 7-Azaindolyl Derivative Ligands in Organoplatinum(II) Complexes: Toward Stereo and Regio-Selective C-H Bond Activation Wang‡ S., Zhao S.B.
11:00 01292 Silane/Imido Coupling Route to Compounds with Nonclassical Si-H Interactions Nikonov‡ G.
11:20 01293 Design and Study of New Coordination Complexes for the Selective Oxidation of Hydrocarbons based on the CH Activation Reaction Periana‡ R.A.
11:40 End of Session

IN3CC-Mariner 5

Macromolecular and Supramolecular Chemistry (Joint with MS and OR) (joint with OR4)

Organizer(s) - Bruce Grindley
Chair(s) - Bruce Grindley

08:00 01294 Multivalent Glycodendrimers toward the Inhibition of Bacterial Adhesion to Host Tissues Roy‡ R., Mohamed T., Shiao T.C., Lagnoux D., Deguise I., Benhamioud K.
08:40 01295 Recognition in Aqueous Solution: Receptors, Enzyme Pockets, and Solvation Hof F.
09:00 01296 Molecular Origami: Towards Urea-Linked Heterocyclic Macrocycles and Foldamers Xing L., Tang N., Navasero N., Mousseau J., Hoang J., Madwar C., Ziener U., Sutherland T.C., Cuccia L.A.
09:20 01297 Liquid Crystalline Behaviour of Hydrogen-Bonded Complexes of Poly(pyridylpyridinium dodecyl methacrylate) Bromide and Functionalized Molecules Sallenave X., Bazuin C.G.
09:40 Coffee Break
10:00 01298 Solid Phase Synthesis of Ion Channels Luong H., Fyles T.M.
10:20 01299 Dendrons/Dendrimers as Reactive Quantized Building Blocks for Nanoscale Organic Syntheses Huang B., Pulgam V.R., Swanson D.R., Tomalia‡ D.A.
11:00 End of Session


REMINDER
11:00 Merck Frosst Centre for Therapeutic Research Award Lecture presented by Robert Batey in CC-Port Royal C1

IN6CC-Mariner 2

Semiconductor and Metal Nanoparticles: Synthesis, Properties and Applications (Joint with MT) (joint with MT8)

Organizer(s) - Matthew Moffitt and Michael Wolf
Chair(s) - Gregory Scholes

08:40 01300 Exploiting Energy Transfer in Hybrid Nanoparticle Systems Feldmann‡ J.
09:20 01301 A Sequential Self-Assembly Route to Three-Dimensional Block Copolymer-Semiconducting Nanoparticle Photonic Arrays with Structural Hierarchy Moffitt M.G., Yusuf H., Kim W.-G.
09:40 Coffee Break
10:00 01302 Electronic Efefcts and Applications of Molecular Spring Assemblies of Nanoparticles and Nanowires Kotov‡ N.A., Lee J., Govorov A.O.
10:40 01303 Surface Chemistry Tailoring of Group IV Semiconductor Nanoparticles Prepared via Metal Hydride Reduction of MX4 (M = Si, Ge; X = Cl, Br, I) Fok E., Veinot J.G.C.
11:00 01304 Pyrolysis of Highly Metallized Polymers: Ceramic Thin Films Containing Magnetic CoFe Alloy Nanoparticles from a Polyferrocenylsilane with Pendant Cobalt Clusters Liu K., Manners I.
11:20 01305 Nanoparticles with a Magnetic Core and an Organic-Inorganic Shell Bronstein L.M., Huang X., Retrum J.R., Stein B.D., Dragnea B.
11:40 End of Session

IN7DH-Baronet 6

General

Organizer(s) - Neil Burford
Chair(s) - Pierre Kennepohl

08:00 01306 Preparation and Properties of Open Framework Solids from Metal Organophosphonate and Organosulfonate Building Blocks Shimizu G.K., Mahmoudkhani A.H., Taylor J.
08:20 01307 Magnetic and Optical Birefringence Properties of Cyanoaurate-Based Coordination Polymers Leznoff D.B.
08:40 01308 Solution and Solid-State Structures of Mixed nBuLi/ NCN "Pincer" Li Aggregates: Unusual Binding Modes in Organolithium Chemistry Chase P.A., Lutz M., Spek A.L., van Klink G.P.M., van Koten G.
09:00 01309 Experimental and Theoretical Studies of Thiazyl Radical Dimers. Relationship of a Magnitude of Singlet-Triplet Gap and a Degree of Diradical Character Decken A., Kowalczyk R.M., McInnes E.J. L., Passmore J., Shuvaev K.V., Thompson L.T.
09:20 01310 Reactivity Studies of Thermally Stable, Terminal and Doubly Bridging Electrophilic Aminophosphinidene (PNR2) Complexes Graham T.W., Udachin K.A., Carty A.J.
09:40 Coffee Break
10:00 01311 The Coordination Chemistry of 2-(2'-Anilinyl)-4,4-dimethyl-2-oxazoline Gossage R.A.
10:20 01312 Catalytically Relevant Ion-Molecule Chemistry McIndoe J.S., Henderson M., Kwok S.
10:40 01313 Toward Understanding the Chemistry of Biologically Relevant Bismuth-Thiolate Complexes Burford N., Phillips H.A.
11:00 01314 The Structure of Lead Glutathione Complexes in Aqueous Solution Mah V. W., Jalilehvand F.
11:20 01315 Microwave-Assisted Synthesis of Re and 99mTc-Metallocarborane Complexes: A New Strategy for the Preparation of Serotonin-Targeted Molecular Imaging Agents Louie A.S., Green A., Causey P., Armstrong A., Valliant J.F.
11:40 End of Session


Wednesday PM

IN2CC-Port Royal C2

Ligand Design in Transition Metal Chemistry

Organizer(s) - Mark Stradiotto
Chair(s) - Christopher Kozak

13:00 01419 Reactions of PCl2[N(iPr)2] on and off Metal Centers: Toward Chelating Bis(phosphenium) Dications Baker‡ R.T., Keaton R.J., Scott B.L.
13:20 01420 Tuning Spin States and Reactivity Patterns at Pseudetrahedral Metal Centers Peters‡ J.C., Thomas C.M., Lu C.C., Mehn M.P., Whited M.T., Mankad N.P.
13:40 01421 From Pyrroles to Isoindolines: The Challenge of Synthesizing 1,4-Diimine Complexes of Late Transition Metals Foley S.R., Chitanda J.M.
14:00 01422 Ligands for the Catalytic Hydrogenation and Asymmetric Hydrogenation of Polar Bonds Morris‡ R.H.
14:20 01423 Influence of Anionic Ligands on Regioselectivity of Rhodium-Catalyzed Alkyne Hydrothiolation Love J.A.
14:40 01424 Diammino(o-benzoquinonediimine)ruthenium Dichloride: Towards 50% p-Back-Donation Lever A.B.P., Gorelsky S.I., Rusanova J., Rusanov E., Popescu R., Christendat D., Beaulac R., Reber C., Farah A.
15:00 Coffee Break
15:20 01425 Structural and Reactivity Studies of Neutral, Cationic, and Zwitterionic Rh(I) and Ir(I) Coordination Complexes of Donor-Functionalized Indene Ligands Cipot J., Stradiotto M.
15:40 01426 New P,N Containing Hemilabile Ligands for Mono- and Binuclear Complexes Bierenstiel M., Cowie M.
16:00 01427 Unique Reactivity of Tris(3-methylindolyl)phosphine Yu J.O., Lam E., Browning C.S., Farrar D.H.
16:20 01428 Nonamethylfluorene: Synthesis and Coordination Chemistry Bazinet P.R., Tupper K., Tilley T.D.
16:40 01429 Mechanistic Shifts in the Hydroboration of Vinyl Arenes with Pinacol Borane Crudden C.M., Edwards D., Hleba Y.B.
17:00 End of Session

IN3CC-Port Royal C1

Macromolecular and Supramolecular Chemistry (Joint with MS and OR) (joint with OR4)

Organizer(s) - Bruce Grindley
Chair(s) - Bruce Grindley


REMINDER
13:00 Boehringer Ingelheim Award Lecture presented by Jason Kennedy in CC-Highland 7

13:40 01430 Rotaxanes as Ligands for Molecular Machines and Metal Organic Frameworks Davidson G.J.E., Hoffart D.J., Mercer D.J., Tiburcio J., Vella S.J., Loeb‡ S.J.
14:20 01431 Design, Synthesis and Application in Catalysis of Host-Rotaxanes Schmitzer A.R., Noujeim N., Salhi A.
14:40 01432 Van der Waals Nanocapsules of Amphiphilic Calixarenes Ananchenko G.S., Pojarova M., Udachin K.A., Ripmeester J.A., Coleman A.W.
15:00 Coffee Break
15:20 01433 Thiazine-1,1-Dioxide as a Hydrogen-Bond Donating Subunit and the Self-Assembly of Artificial Sequence-Specific Double Helices Wisner J.A., Li J.
15:40 01434 Host Properties of a Fluorescent Cucurbit[6]uril Analogue Wagner B.D., Boland P.G., Isaacs L., Lagona J.
16:00 01435 Electron Transfer and Photochemical Reactions of Cucurbit[7]uril-Ferrocene Host-Guest Complexes Macartney D.H., Wang R., Yuan L.
16:20 01436 Nano Toys and Nano Art: How Fun and Beauty Inspire Chemical Creativity Stoddart‡ J.F.
17:00 End of Session

IN6CC-Mariner 2

Semiconductor and Metal Nanoparticles: Synthesis, Properties and Applications (Joint with MT) (joint with MT8)

Organizer(s) - Matthew Moffitt and Michael Wolf
Chair(s) - Jonathan Veinot

13:00 01437 SEM, TEM and EDX Characterization of Granular Activated Carbon Impregnated with Nanoscopic Cu and CuO Westreich P., Fortier H., Dahn J.R.
13:20 01438 Synthesis of Colloidal Upconverting NaYF4 Nanocrystals Doped with Er3+, Yb3+ and Tm3+, Yb3+ via Thermal Decomposition of Lanthanide Trifluoracetate Precursors Boyer J.-C., Bédard M., Vetrone F., Cuccia L.A., Capobianco J.A.
13:40 01439 Synthesis of TiO2 Nanomaterials and Applications in Biosensor Design Chen A., Peng X., Holt-Hindle P., Liu S.
14:00 01440 Synthesis and Characterization of Group 11 Trimethylsilylchalcogenolate Reagents: Precursors in the Assembly of Ternary Clusters Corrigan J.F., Borecki A.E.
14:20 01441 Understanding Structure-Function Relationships in Molecule-Linked Au Nanoparticle Films: A Bottom-Up Approach Dhirani‡ A.-A., Dunford J., Suganuma Y., Zabet-Khosousi A.
15:00 Coffee Break
15:20 01442 Hydrogen Silsesquioxane: A Molecular Precursor for Silicon Nanostructures Hessel C., Veinot J.G.C.
15:40 01443 Development of Superparamagnetic Materials for Biological Applications Somaskandan K., Veres T., Simard B.
16:00 01444 Synthesis of Mixed-Chalcogen Cadmium and Mercury Nanoparticles from a Sulfur-Selenium Single Source Precursor Turner E.A., Huang Y., Corrigan J.F.
16:20 End of Session

IN7DH-Baronet 6

General

Organizer(s) - Neil Burford
Chair(s) - Neil Burford

13:00 01445 Electronic Structure of Ruthenium Olefin Metathesis Catalysts - Experimental and Theoretical Considerations Kennepohl P.
13:20 01446 Characterization and Catalytic Studies of a Novel Ruthenium bis IMes Complex Blacquiere J.M., Dharmasena U.L., Foucault H.M., Fogg D.E.
13:40 01447 Copper(I) Complexes with Exceptionally Long Excited State Lifetimes McCormick T.M., Liu Q.-D., Jia W.-L., Wang S.
14:00 01448 Synthesis and Characterization of Complexes of the Type RuHX(diamine)(PPh3)2 and their Use as Catalysts Clapham S.E., Guo R., Zimmer-De Iuliis M., Rasool N., Lough A., Morris R.H.
14:20 01449 Synthesis of s-trans-Chromium Dienes and g3-Allyl Chromium-Tin Complexes Norman D.W., Stryker J.M.
14:40 01450 Development of a Homogeneous Rhodium Oxidation Catalyst Praetorius J.M., Allen D.P., Webb J.D., Crudden C.M.
15:00 Coffee Break
15:20 01451 Studies in Optimizing the Suzuki-Miyaura Reaction Mitchell E.A., Baird M.C.
15:40 01452 Ruthenium Metathesis Catalysts Containing Catecholate Ligands: Activity versus Ligand pKa Monfette S., Fogg D.E.
16:00 01453 Transition Metal Trialkyls: Lewis-Acidity, Catalytic Activity, and Synthetic Approaches Towards Novel Topologies Fekl U., Hofmann A., Ren R., Hsieh V., De Crisci A.
16:20 End of Session


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